2. THIS IS JEOPARDY! Up To And Including Energy Changes in Chemical Reactions!

3. Energy Changes SolutionsEquilibrium IIEquilibriumReaction Kinetics 100 200 300 400 500

4. Energy Changes 100 If heat is written down in a chemical equation as a reactant, is the reaction endothermic or exothermic? Does the reaction have a positive or negative value of ΔH? The reaction is endothermic, and it has a positive value of ΔH.

5. Energy Changes 200 Temperature is a measure of the average energy of a substance, while heat is actual energy moving from a warmer object to a cooler object. Explain the difference between heat and temperature.

6. Energy Changes 300 Which of the following is an endothermic change? D. Ice melting requires the ice to absorb energy. a.Hot coffee cooling to room temperature b.Steam condensing to water on a cold window c.Frost forming on a windshield d.Ice melting

7. Energy Changes 400 What is the first law of thermodynamics? Energy cannot be created or destroyed – it can only change forms.

8. Energy Changes 500 How would you solve the following problem if it came up on a departmental exam? Use Hess’ Law – all of the molecules are formed by reactions with their elements in their standard states.

9. Solutions 100 This is what the abbreviation ppm stands for. Parts per milion

10. Solutions 200 When a solution has more solute in it than it is supposed to be able to hold at a given temperature, we call the solution ___________________. Supersaturated

11. Solutions 300 What is the key fact that allows for the derivation of the dilution equation, C1V1 = C2V2? Before and after the dilution, the number of moles of solute are the same.

12. Solutions 400 Daily Double What is the mass of a 4.5% ethanol solution containing 0.6 g of ethanol? 13.3 grams

13. Solutions 500 HCl is added to a saturated solution of NaCl. Explain why NaCl precipitates out of the solution, using Le Chatelier’s Principle! The solution contains a system of NaCl dissolving to form Na + and Cl - at chemical equilibrium. The adding of HCl is a stress that increases Cl -, and to offset it, NaCl is formed.

14. Reaction Kinetics 100 Is the reaction pictured in the diagram endothermic or exothermic? How can you tell? Exothermic, energy of the products is lower than the energy of the reactants.

15. Reaction Kinetics 200 What is the transition state, or activated complex? The transition state is the complex that exists between reactants and products, and it has incredibly high energy and only lasts for a very short time.

16. Reaction Kinetics 300 According to the collision theory, what has to happen in order for two particles that collide to chemically react? The particles must strike with enough energy, as well as with the proper orientation.

17. Reaction Kinetics 400 Catalysts increase the rate of a chemical reaction by decreasing the energy required for an effective collision – in other words, they lower that energy hill. What is the role of a catalyst in a chemical reaction? How does it affect the energy of the transition state?

18. Reaction Kinetics 500 Imagine that you have a gaseous system that is reacting, but you can’t measure the concentration of the chemicals involved. How else could you measure the speed of the reaction? Measure the change in pressure of the system.

19. Equilibrium 100 Imagine that at chemical equilibrium, the rate of the forward reaction was greater than the rate of the reverse reaction. What would you say about that chemical equilibrium? That’s impossible! At equilibrium, the rate of the forward reaction is ALWAYS equal to the rate of the reverse reaction.

20. Equilibrium 200 When we are writing an equilibrium constant expression, what phases of matter do we leave out of it? Solids and liquids.

21. Equilibrium 300 A chemical equilibrium has a K eq value of approximately 5 x 10 89. Which of the following is true? a.The chemical reaction occurs very quickly b.The reaction essentially goes to completion c.There are virtually no products present at equilibrium d.The denominator of the equilibrium constant expression is very high b. The reaction essentially goes to completion

22. Equilibrium 400 If you increase the pressure of a gaseous system, to which side of the chemical equation will the equilibrium shift? It will shift to the side with the fewest moles of gas.

23. Equilibrium 500 Look at the following chemical reaction. Which of the following would NOT shift the position of the equilibrium? H 2 O (l) + H 2 O (l) → H 3 O + (aq) + OH - (aq) a.Lowering concentration of OH - b.Increasing volume of container c.Increasing temperature d.Adding a catalyst Neither B or D will affect it – changing pressure only affects gases at equilibrium.

24. Equilibrium II 100 Imagine that you have a system that initially only has products in it. Initially, is the rate of the forward reaction faster or the reverse reaction faster? The rate of the reverse reaction is faster – initially there are no reactants, so the forward reaction can’t even occur.

25. Equilibrium 200 What is a steady-state process? A process in which products are constantly removed and new reactants are constantly added.

26. Equilibrium 300 What factor that shifts equilibrium also changes the value of the equilibrium constant? Temperature

27. Equilibrium II 400 Examine the following graph. Are the reactants or products favoured at chemical equilibrium? From what you are given, it is impossible to tell

28. Equilibrium II 500 I wanted to put an I.C.E. box problem here, but decided that would be hard to work out. What is the first step in solving an I.C.E. box problem if you know the concentrations of one chemical initially AND at equilibrium? Calculate the changes in concentration of each species based on the change in the one you know.

29. VeggieTales 100 Picture Daily Double

30. VeggieTales 100 The name of the following character.

31. VeggieTales 200 If you like to talk to tomatoes, If a squash can make you _______.

32. VeggieTales 300 The nationality of the green peas.

33. VeggieTales 400 The name of the carrot on VeggieTales.

34. VeggieTales 500 Audio Daily Double

35. VeggieTales 500 The character who sings this song.

36. Double Jeopardy

37. Final Jeopardy Your regular Sunday School Teacher.

38. Final Jeopardy The name of Jeff’s son.