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Published byImogen Sparks Modified over 9 years ago
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Transition metals catalysts Catalysts lower activation energies allowing a chemical reaction to go faster. Heterogenous catalyst: different phase as reactants. Homogenous catalyst: same phase.
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Transition metals as catalysts Transition metals are good catalysts because: o they have the availability of 3d and 4s electrons and similar successive ionization energies which allow them to change easily between different oxidation states (homogenous catalysis) o have empty orbitals which can be used to make temporary bonds (heterogenous catalysts).
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Heterogenous catalysis Nickel in the conversion of alkenes into alkanes. Iron in the Haber process Manganese dioxide in the decomposition of hydrogen peroxide. Palladium and platinum in a catalytic converter. Cobalt in manufacture of vitamin B 12
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Homogenous catalysis Overall: S 2 O 8 2 (aq) + 2I - (aq) 2SO 4 2- (aq) + I 2 (s) Using catalyst Fe 3+ 2Fe 3+ (aq) + 2I - (aq) 2Fe 2+ (aq) + I 2 (s) 2Fe 2+ (aq) + S 2 O 8 2- (aq) 2Fe 3+ (aq) + 2SO 4 2- (aq)
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