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Displacement reactions
recombine ions Acid-Base reactions H+ transfer Fe2O3 (s) + Al (s) Al2O3 (s) + Fe (l) thermite reaction Oxidation-Reduction reactions (redox) e- transfer Fe2O3 = iron ( ) III oxide Fe3+ Fe (l) = Fe0 Fe3+ has_____ protons 26 Fe0 has _____ protons 26 Fe3+ has ____ electrons 23 Fe0 has ____ electrons 26 Fe3+ gained 3 electrons gaining e- = reduction reducing the oxidation state 3+
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Fe2O3 (s) + Al (s) Al2O3 (s) + Fe (l) Al (s) = Al0 Al2O3 aluminum oxide Al0 has _____ electrons 13 Al3+has ______ electrons 10 oxidation state = oxidation state = 3+ Al0 loses___ e- 3 losing e- = oxidation increase oxidation number 3+ LEO GER Lose Electrons Oxidation Gain Electrons Reduction
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Rules for oxidation numbers
1. Oxidation number for elements is zero. N2, O2, Na(s), Co(s), He (g) Oxidation number of monatomic ions is the same as their charge Group IA = +1 Al3+, Zn2+, Cd2+, Ag+ Group IIA = +2 Oxidation number of oxygen in most compounds is –2. Exceptions: H2O2, O2- (peroxides) –1 4. Oxidation number of hydrogen is +1 Exceptions: bonded to metals LiH 5. Fluorine is always –1. Other halogens are –1. Exceptions: bonded to O, they are positive
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Assign oxidation numbers to all of the elements:
Li2O Li = +1 O = -2 PF3 P = +3 F = -1 HNO3 H = +1 N = +5 O = -2 MnO4- Mn = +7 O = -2 Cr2O72- Cr = +6 O = -2
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What is the oxidation state of the highlighted element?
P2O5 +5 diphosphorous pentoxide NaH -1 sodium hydride SnBr4 +4 tin (IV) bromide BaO2 -1 barium peroxide
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Redox reactions +1 +2 Zn (s) + 2H+ (aq) H2 (g) + Zn 2+ Zn +2 increase oxidation state lose electrons oxidized reducing agent H +1 decrease oxidation state gain electrons reduced oxidizing agent
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+1 -2 2H2(g) + O2 (g) 2H2O(l) H loses or gains electrons is oxidized or reduced oxidizing or reducing agent O loses or gains electrons is oxidized or reduced oxidizing or reducing agent
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+7 +3 +4 2H2O + Al(s) + MnO4- Al(OH)4- + MnO2 H2O What is being oxidized? Al What is oxidation? MnO4- LEO Al(OH)4- MnO2 How many e-? What is being reduced? GER What is the reducing agent?
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What is the oxidation state of S in each of these
compounds: H2S S = -2 H = +1 S8 S = SCl2 S = +2 Cl = -1 Na2SO3 S = +4 O = -2 Na = +1 SO42- S = +6 O = -2 Which of these compounds can not act as a reducing agent? Which of these compounds can not act as a oxidizing agent?
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+4 -2 +1 -2 +2 -2 +1 +2 -2 +1 Cd(s) + NiO2 + 2H2O Cd(OH)2 + Ni(OH)2 What is being oxidized? What is being reduced? What is the oxidizing agent? What is the reducing agent? How many electrons are transferred?
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