1. Nonrenewable Energy

2. Core Case Study: How Long Will the Oil Party Last?  Saudi Arabia could supply the world with oil for about 10 years.  The Alaska’s North Slope could meet the world oil demand for 6 months (U.S.: 3 years).  Alaska’s Arctic National Wildlife Refuge would meet the world demand for 1-5 months (U.S.: 7-25 months).

3. Core Case Study: How Long Will the Oil Party Last?  We have three options: Look for more oil. Use or waste less oil. Use something else. Figure 16-1

4. TYPES OF ENERGY RESOURCES  About 99% of the energy we use for heat comes from the sun and the other 1% comes mostly from burning fossil fuels. Solar energy indirectly supports wind power, hydropower, and biomass.  About 76% of the commercial energy we use comes from nonrenewable fossil fuels (oil, natural gas, and coal) with the remainder coming from renewable sources.

5. TYPES OF ENERGY RESOURCES  Nonrenewable energy resources and geothermal energy in the earth’s crust. Figure 16-2

6. TYPES OF ENERGY RESOURCES  Commercial energy use by source for the world (left) and the U.S. (right). Figure 16-3

7. TYPES OF ENERGY RESOURCES  Net energy is the amount of high-quality usable energy available from a resource after subtracting the energy needed to make it available.  Remember the second law of thermodynamics!  Net energy ratio – useful energy produced/energy used to produce it

8. Net Energy Ratios  The higher the net energy ratio, the greater the net energy available. Ratios < 1 indicate a net energy loss. Figure 16-4

9. OIL  Crude oil (petroleum) is a thick liquid containing hydrocarbons that we extract from underground deposits and separate into products such as gasoline, heating oil and asphalt. Only 35-50% can be economically recovered from a deposit. As prices rise, about 10-25% more can be recovered from expensive secondary extraction techniques. ○ This lowers the net energy yield.

10. OIL  Refining crude oil: Based on boiling points, components are removed at various layers in a giant distillation column. The most volatile components with the lowest boiling points are removed at the top. Figure 16-5

11. OIL  World’s largest business  Eleven OPEC (Organization of Petroleum Exporting Countries) have 78% of the world’s proven oil reserves and most of the world’s unproven reserves. An oil reserve is an identified deposit from which crude oil can be extracted profitably at current prices and current technology.

12. 2007 World Proved Reserves  After global production peaks and begins a slow decline, oil prices will rise and could threaten the economies of countries that have not shifted to new energy alternatives.  Top three oil consuming nations U.S. (60%) China (33%) Japan (100%) Source: U.S Department of Energy, Energy Information Administration Energy Information Administration

13. Oil Refining Capabilities  Organization for Economic Co-operation and Development (OECD) countries control most oil refining.  Supply and demand economics are therefore interrupted by a multi- stage process dictating the supply.

14. Historic Oil Prices  Source: Lindstrom, Kirk. Inflation adjusted oil prices fall on strong USD. Seeking Alpha. 19 Oct, 2008. Retrieved 26 Mar, 2009 from http://seekingalpha.com/article/100560-inflation-adjusted-oil-prices-fall-on-strong-usd

15. As Oil Prices Rise…  Prices of food and products produced from petrochemicals will rise.  People will necessary move down the food chain.  Food production may become more localized.  More land will be used to produce renewable biomass crops.  Air travel and air freight may decline.  Re-urbanization

16. Case Study: U.S. Oil Supplies  The U.S. – the world’s largest oil user – has only 2.9% of the world’s proven oil reserves.  U.S oil production peaked in 1974 (halfway production point).  About 60% of U.S oil imports goes through refineries in hurricane-prone regions of the Gulf Coast.

17. Alaskan Oil Pipeline Carries 2 million barrels a day of crude oil from the Prudhoe Bay oil field 789 miles south to Southern Alaska to be loaded onto tankers destined for refineries. Represents 25% of the U.S. crude oil reserves.

18. OIL  Burning oil for transportation accounts for 43% of global CO 2 emissions. Figure 16-7

19. CO 2 Emissions  CO 2 emissions per unit of energy produced for various energy resources. Figure 16-8

20. Heavy Oils  Heavy and tarlike oils from oil sand and oil shale could supplement conventional oil, but there are environmental problems. High sulfur content. Extracting and processing produces: ○ Toxic sludge ○ Uses and contaminates larges volumes of water ○ Requires large inputs of natural gas which reduces net energy yield. ○ Deforestation

21. Oil Sands  Bitumen can be extracted  Athabascan Oil Sands deposits equal in area to U.S. states of MD and VA.  Supply 1/5 of Canadian energy needs.  Production costs high ($13/barrel vs. $1-2 for conventional production.  1.8 mt of oil sand = 1 barrel of oil.  China invested heavily.

22. Canadian Oil Sand Pit Mine

24. Athabascan River Surface Water Allocations

25. Oil Shales  Oil shales contain a solid combustible mixture of hydrocarbons called kerogen. Figure 16-9

26. Figure 16-10

27. When Does the Oil Party End?

28. NATURAL GAS  Natural gas consists mostly of methane and other gaseous hydrocarbons. Conventional natural gas ○ found above reservoirs of crude oil. ○ When a natural gas-field is tapped, gasses are liquefied and removed as liquefied petroleum gas (LPG). Unconventional natural gas ○ Coal bed methane gas ○ Methane hydrate bubbles of methane trapped in ice crystals deep under the arctic permafrost and beneath deep-ocean sediments

29. Natural Gas Processing

30. Natural Gas Production

31. NATURAL GAS  Some analysts see natural gas as the best fuel to help us make the transition to improved energy efficiency and greater use of renewable energy. Figure 16-11

32. COAL  Coal is a solid fossil fuel that is formed in several stages as the buried remains of land plants that lived 300-400 million years ago. Figure 16-12

33. COAL  Most abundant fossil fuel  Generates 62% of world’s electricity and is used to make 75% of its steel  Anthracite (98% carbon) is most desirable but least common.  Lower grades of coal have increasing traces of sulfur, toxic mercury, and radioactive materials that are released upon burning.  Extraction by subsurface mining, area strip mining, contour strip mining, and mountaintop removal are environmentally damaging.

34. Fig. 16-13, p. 369 Waste heat Coal bunker Turbine Cooling tower transfers waste heat to atmosphere Generator Cooling loop Stack Pulverizing mill Condenser Filter Boiler Toxic ash disposal

35. COAL  Coal reserves in the United States (27%), Russia (17%), and China (13%) could last hundreds to over a thousand years. In 2005, China and the U.S. accounted for 53% of the global coal consumption.

36. COAL  Coal is the most abundant fossil fuel, but compared to oil and natural gas it is not as versatile, has a high environmental impact, and releases much more CO 2 into the troposphere. Figure 16-14

37. COAL Synfuels  Coal can be converted into synthetic natural gas (SNG or syngas) and liquid fuels (such as methanol or synthetic gasoline) that burn cleaner than coal. Requires mining 50% more coal Costs are high. Burning them adds more CO 2 to the troposphere than burning coal.

39. COAL  Since CO 2 is not regulated as an air pollutant and costs are high, U.S. coal-burning plants are unlikely to invest in coal gasification. Figure 16-15

40. Clean Coal Technology Multiple technologies aimed at cleaning coal and containing its emissions Coal washing Wet scrubbers (flue gas desulfurization systems) Low-NO x burners Electrostatic precipitators Oxy-fuel combustion Pre-combustion capture

41. Clean Coal Technology  Regardless of method, the CO2 must be sequestered – either in a commercially viable product or stored deep underground or in the oceans. 1. CO2 pumped into disused coal fields displaces methane which can be used as fuel 2. CO2 can be pumped into and stored safely in saline aquifers 3. CO2 pumped into oil fields helps maintain pressure, making extraction easier

42. NUCLEAR ENERGY  When isotopes of uranium and plutonium undergo controlled nuclear fission, the resulting heat produces steam that spins turbines to generate electricity. The uranium oxide consists of about 97% nonfissionable uranium-238 and 3% fissionable uranium-235. The concentration of uranium-235 is increased through an enrichment process.

43. Fig. 16-16, p. 372 Small amounts of radioactive gases Uranium fuel input (reactor core) Control rods Containment shell Heat exchanger Steam Turbine Generator Waste heat Electric power Hot coolant Useful energy 25%–30% Hot water output Pump Coolant Pump Moderator Cool water input Waste heat Shielding Pressure vessel Coolant passage Water Condenser Periodic removal and storage of radioactive wastes and spent fuel assemblies Periodic removal and storage of radioactive liquid wastes Water source (river, lake, ocean)

44. NUCLEAR ENERGY  After three or four years in a reactor, spent fuel rods are removed and stored in a deep pool of water contained in a steel-lined concrete container. Figure 16-17

45. NUCLEAR ENERGY  After spent fuel rods are cooled considerably, they are sometimes moved to dry-storage containers made of steel or concrete. Figure 16-17

46. Fig. 16-18, p. 373 Decommissioning of reactor Fuel assemblies Reactor Enrichment of UF 6 Fuel fabrication (conversion of enriched UF 6 to UO 2 and fabrication of fuel assemblies) Temporary storage of spent fuel assemblies underwater or in dry casks Conversion of U 3 O 8 to UF 6 Uranium-235 as UF 6 Plutonium-239 as PuO 2 Spent fuel reprocessing Low-level radiation with long half-life Geologic disposal of moderate & high-level radioactive wastes Open fuel cycle today “Closed” end fuel cycle

47. What Happened to Nuclear Power?  After more than 50 years of development and enormous government subsidies, nuclear power has not lived up to its promise because: Multi billion-dollar construction costs. Higher operation costs and more malfunctions than expected. Poor management. Public concerns about safety and stricter government safety regulations.

48. Case Study: The Chernobyl Nuclear Power Plant Accident  The world’s worst nuclear power plant accident occurred in 1986 in Ukraine.  The disaster was caused by poor reactor design and human error.  By 2005, 56 people had died from radiation released. 4,000 more are expected from thyroid cancer and leukemia.

49. NUCLEAR ENERGY  In 1995, the World Bank said nuclear power is too costly and risky.  In 2006, it was found that several U.S. reactors were leaking radioactive tritium into groundwater. Figure 16-19

50. NUCLEAR ENERGY  A 1,000 megawatt nuclear plant is refueled once a year, whereas a coal plant requires 80 rail cars a day. Figure 16-20

51. NUCLEAR ENERGY  Terrorists could attack nuclear power plants, especially poorly protected pools and casks that store spent nuclear fuel rods.  Terrorists could wrap explosives around small amounts of radioactive materials that are fairly easy to get, detonate such bombs, and contaminate large areas for decades.

52. NUCLEAR ENERGY  When a nuclear reactor reaches the end of its useful life, its highly radioactive materials must be kept from reaching the environment for thousands of years.  At least 228 large commercial reactors worldwide (20 in the U.S.) are scheduled for retirement by 2012. Many reactors are applying to extent their 40-year license to 60 years. Aging reactors are subject to embrittlement and corrosion.

53. NUCLEAR ENERGY  Building more nuclear power plants will not lessen dependence on imported oil and will not reduce CO 2 emissions as much as other alternatives. The nuclear fuel cycle contributes to CO 2 emissions. Wind turbines, solar cells, geothermal energy, and hydrogen contributes much less to CO 2 emissions.

54. NUCLEAR ENERGY  Scientists disagree about the best methods for long-term storage of high-level radioactive waste: Bury it deep underground. Shoot it into space. Bury it in the Antarctic ice sheet. Bury it in the deep-ocean floor that is geologically stable. Change it into harmless or less harmful isotopes.

55. New and Safer Reactors  Pebble bed modular reactor (PBMR) are smaller reactors that minimize the chances of runaway chain reactions. Figure 16-21

56. Fig. 16-21, p. 380 Each pebble contains about 10,000 uranium dioxide particles the size of a pencil point. Pebble detail Silicon carbide Pyrolytic carbon Porous buffer Uranium dioxide Graphite shell Helium Turbine Generator Pebble Core Hot water output Recuperator Reactor vessel Water cooler Cool water input

57. New and Safer Reactors  Some oppose the pebble reactor due to : A crack in the reactor could release radioactivity. The design has been rejected by UK and Germany for safety reasons. Lack of containment shell would make it easier for terrorists to blow it up or steal radioactive material. Creates higher amount of nuclear waste and increases waste storage expenses.

58. NUCLEAR ENERGY  Nuclear fusion is a nuclear change in which two isotopes are forced together. No risk of meltdown or radioactive releases. May also be used to breakdown toxic material. Still in laboratory stages.  There is a disagreement over whether to phase out nuclear power or keep this option open in case other alternatives do not pan out.

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60. Resources Wood, David & Saeid Mokhatab. "Control & influences on world oil price - Part 2: How value is extracted from oil along its supply chains." Oil & Gas Financial Journal. Nov 2006. PennWell Corporation. 30 Mar 2009.