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Published byFrederica McCormick Modified over 9 years ago
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Electronic Spectroscopy Hitachi-HiTec
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Electronic Excitation Model A ~ X ~ Excitation (Absorption) Radiationless decay (vibrational relaxation) Fluorescence (Fast radiative decay) Internal conversion (Slowish non-radiative decay)
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Electronic Excitation Model A ~ X ~ a ~ Excitation Intersystem crossing Radiationless decay (vibrational relaxation) Phosphorescence (Slow radiative decay) Intersystem crossing (Slow non-radiative decay)
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Franck-Condon Principle The intensities of observed peaks in UV-Vis spectra depend on the overlap between the initial and final vibronic states A ~ X ~ A ~ X ~ Good Overlap-Strong Peaks Eh Overlap-Weak Peaks
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Fluorescence Spectra Hitachi-HiTec A Plasma Display Panel Fluorescence Spectrum Excite mostly in the UV
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Fluorescence Spectra A neat fluorescence spectrum tool for assorted fluoro-cores: http://www.bdbiosciences.com/ca/research/multicolor/spectrum_viewer/index.jsp
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