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Electronic structure of ZnO from x-ray spectroscopy Andrew Preston

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Presentation on theme: "Electronic structure of ZnO from x-ray spectroscopy Andrew Preston"— Presentation transcript:

1 Electronic structure of ZnO from x-ray spectroscopy Andrew Preston andrew@preston.co.nz

2 Co-authors Ben Ruck –Victoria University of Wellington Louis Piper, Alex DeMasi and Kevin Smith –Boston University Andre Schleife, Frank Fuchs and Friedhelm Bechstedt –Friedrich-Schiller-Universitat Jessica Chai and Steve Durbin –University of Canterbury

3 Zinc oxide

4 Zn 2+ = [Ar]3d 10 O 2- = [Ne]

5 Zinc oxide

6 Quantum mechanics –Discrete states for energy eigenvalues Crystalline material –Crystal momentum affects eigenvalues ZnO electronic structure

7 X-ray absorption (XAS) EfEf Empty Filled

8 X-ray emission (XES) Empty Filled

9 ZnO electronic structure

10 ZnO XAS and XES

11 ZnO anisotropy ZnO crystal O p orbitals

12 ZnO anisotropy

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14 ZnO XAS and XES

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17 ZnO RXES

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22 ZnO p xy band structure

23 ZnO p z band structure

24 arXiv:0805.4641 andrew@preston.co.nz


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