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West Valley High School
SOLUTIONS Chapter 12 West Valley High School General Chemistry Mr. Mata
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Standard 5 Students know that temperature, pressure, and surface area affect the dissolving process.
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Essential Question: What are the components of a solution and how do solutions, suspensions, and colloids differ from one another?
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What is a Solution? Solution = homogeneous mixture of two or more substances. (solute & solvent) Solute = substance being dissolved. Solvent = substance doing the dissolving. Homogeneous mixture = completely dissolved & uniform solute in solvent Aqueous solution = solution in which the solvent is water.
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Parts of a Solution
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Homogeneous vs. Heterogeneous
24-karat gold is pure gold = homogeneous 14-karat gold is an alloy (mixture) Au, Ag, Cu = heterogeneous 14-karat gold is 14/24 (58.3%) gold
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Solubility Terminology
Soluble = substance that can be dissolved. Insoluble = substance that cannot be dissolved. Solubility = measure of how much solute will dissolve in solvent. Miscible = two liquids that dissolve in each other (ex: water & ethanol). Immiscible = two liquids that don’t dissolve in each other (ex: H2O & oil).
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Immiscible Liquids
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Solubility Terminology
SATURATED—contains the maximum amount of solute. UNSATURATED—contains less solute than a saturated solution. SUPERSATURATED—contains more solute than it should.
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Solution Saturations
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Factors affecting Solubility
Stirring (agitation) increases solubility. Surface Area (particle size) smaller size increases surface area: increases sol. Pressure (gases) increased pressure increases gas solubility. Temperature (solids & gases). solids: temp increase = increases solubility gases: temp increase = decrease solubility
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Solution Concentration
Concentration: measure of the amount of solute that is dissolved in a given quantity of solvent. Dilute solution = solution that contains small amount of solute. Concentrated solution = solution that contains a large amount of solute. Molarity (M) = moles of solute/L of soln Units = M or moles/Liter (mol/L).
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Suspensions Suspension – particles in a solvent are so large that they settle to bottom unless agitated. Ex: muddy water Soil particles will sink to bottom. Can be separated from heterogeneous mixtures by filtering.
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Colloids Particles are intermediate in size between those in solutions and suspensions. 1 nanometer (nm) to 1000 nm. Cause mixture to look “cloudy”. Ex: mayonnaise Egg yolk keeps the oil droplets dispersed.
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MOLARITY Molarity (M) = moles of solute Liters of solution
Units in mol/L or M
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A saline solution contains 0. 90 g NaCl in exactly 100 mL of solution
A saline solution contains 0.90 g NaCl in exactly 100 mL of solution. What is the molarity of the solution? M = moles solute Liters of solution 0.90 g NaCl x 1 mol NaCl = 0.02 mol NaCl 58 g NaCl 100 mL x 1 L = 0.1 L 1000 mL M = 0.02 mol = 0.2 mol/L or 0.2 M 0.1 L
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A solution contains 325 g CaCl2 in exactly 2500 mL of solution
A solution contains 325 g CaCl2 in exactly 2500 mL of solution. What is the molarity of the solution? M = moles solute Liters of solution 325 g CaCl2 x 1 mol CaCl2 = mol CaCl2 110 g CaCl2 2500 mL x 1 L = 2.5 L 1000 mL M = 2.95 mol = 1.2 mol/L or 1.2 M 2.5 L
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How many moles of solute are present in 1.5 L of 0.24 M Na2SO4?
M = mol -> mol = ML L 0.24 M Na2SO4 = 0.24 mol/L Na2SO4 Mol = (0.24 mol/L) (1.5L) = 0.36 mol
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How many moles of solute are present in 20 L of 12 M H2SO4?
M = mol -> mol = ML L 12 M H2SO4 = 12 mol/L H2SO4 Mol = (12 mol/L) (20L) = 240 mol
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Percent Solutions What is the percent by volume of ethanol in the final solution when 85 mL of ethanol is diluted with 250 mL of water? %v/v = volume of solute x 100 solution volume %v/v = 85 mL ethanol x 100 = 250 mL H2O = 34% ethanol (v/v)
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Percent Solutions What is the percent by volume of ethanol in the final solution when 300 mL of ethanol is diluted with 600 mL of water? %v/v = volume of solute x 100 solution volume %v/v = 300 mL ethanol x 100 = 600 mL H2O = 50% ethanol (v/v)
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Parts per Million Parts per million (ppm)
Aqueous solutions: 1 ppm = 1000 ng/L The federal limit of lead in tap water is ppm. Express this concentration in ng/L. 0.015 ppm x 1000 ng/L = 15 ng/L 1 ppm
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Parts per Million The federal limit of mercury in tap water is ppm. Express this concentration in ng/L. ppm x 1000 ng/L = .2 ng/L 1 ppm
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Chapter 12 SUTW Prompt Describe the differences between an unsaturated, saturated, and supersaturated solution. Complete a sentence paragraph using the SUTW paragraph format. Hilight using green, yellow, and pink. Due Date: Tomorrow (start of class).
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