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Production of Hydrogen from Renewable Electricity: The Electrolysis Component Workshop on Electrolysis Production of Hydrogen from Wind and Hydropower NREL DC Office, Sept 8,2003.
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Renewable Electricity- Infrastructure Meets DOE Hydrogen Feed Stock Strategy: Primary Indigenous Sources: Wind, “run of river” hydro, solar No carbon-emissions in electricity-hydrogen generation Mature technology, established cost progression But can we meet DOE cost target ? $2.00 per kg at plant gate
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Wind-Electrolysis Integration Process Capabilities: > 90% of energy consumed by cells (@ 20 bar) generator following load trade off between efficiency and cap $. Efficiency inversely proportional to cell surface area (cap$). design to avg efficiency/wind resource: Plant X = 53 kWh/kg Plant 2X = 47.5 kWh/kg “Current sink” characteristic Voltage regulated by cells Response like “leaky capacitor” Value of by-products Electricity on demand Oxygen by-product @ $25 per tonne =.4 cent per kWh D 2 0 ?
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Cost Target Implications Simple Cost Model : $/kg = Efficiency (price of electricity) + [Annual (CRF+O/M)] (Capital Cost per kg/h)÷ [(capacity factor) 8760 h/y] Implications For Annual (CRF +O/M) =20% Capacity Factor =.35 Avg. Efficiency = 50 kWh/kg (=approx 80% wrt HHV) Cost of Wind Electricity`2.5 ¢/kWh3.0 ¢/kWh Cost of Electrolyser (@ Avg Efficiency)$12,000/kg/h$8,000/kg/h
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Two Market Models: Wind-Hydrogen Generation Model Wind- Hydrogen&Electricity Generation Model
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Capacity Factor Matching in Wind- Hydrogen Generation Model Single tier market design: Large-Scale Hydrogen Production Tech Implications Power Conversion: Optimize DC-Wind conversion based on electrolysis cells Optimize cell size to scale of production – cell cost key Maintaining grid stability with high electrolysis penetration Pressurized cell design amenable to distribution pipeline
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Capacity Factor Matching in Wind Hydrogen-Electricity Generation Model Two tier market design: Primary Market : Electricity Secondary Market: Hydrogen Deregulated electricity market design with environmental credits for emission avoidance Capture distributed generation benefit Closer to market Higher value electricity market supports secondary hydrogen production (energy storage) Technology Implications Controls System Cost Key
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Cell Technology Product NameStuart CellEI-250M-PlatformIMET Cell TechnologyUnipolar Gen IIUnipolar Gen II DEPBipolar Production Capacity 5 Nm3/h to 1000 Nm3/h 1000 Nm3/h and greater 50 Nm3/h and greater 1 Nm3/h to 100 Nm3/h Cell PressureAtmospheric up to 25 bars Typical Application Generator Cooling Hydrogen Peroxide Fiber OpticsBus filling station
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Technical Challenges Intermittent operation; long term electrode stability Economic scale of cell; cost highly dependant on cells Gas purity process dynamics: Controlling gas/liquid separation Reducing bypass cell currents Cell pressurization Power conversion & controls
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Conclusions: DOE cost targets are very challenging Early pathways to develop infrastructure: Replace SMR hydrogen under right market conditions (NG conservation/CO2 mitigation): heavy oil upgrading ammonia production Distributed “hydrogen&electricity generation model” may play role in early infrastructure development – if value put on green electricity/green hydrogen.
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