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Boyle’s Law Mathematical relationship between pressure and volume.
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Pressure and Volume – Inverse Relationship For a given sample of gas, as the volume increases, the pressure __________________. The opposite is true, as the volume decreases, the pressure ___________________.
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Look at your data from Monday For 10 data points, calculate the value of the pressure x the volume. For a given sample of gas, at a constant temperature… P x V = k (a constant)
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BOYLE’S Law If temperature is held constant, the product of the initial pressure x volume = the product of a final pressure x volume since each equal the constant. P 1 V 1 = k P 2 V 2 = k P 1 V 1 = k = P 2 V 2 P 1 V 1 = P 2 V 2
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Example 1 – applying Boyle’s Law A diver blows a 0.75 L air bubble 10 m under water. As the bubble rises to the surface, the pressure decreases from 2.25 atm to 1.03 atm. Calculate the volume of the bubble at the surface. Formula: P 1 V 1 = P 2 V 2 V 2 = P 1 V 1 /P 2 V 2 = (2.25 atm)x(0.75 L)/(1.03 atm) V 2 = 1.6 L
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Example 2 – applying Boyle’s Law Under a pressure of 0.988 atm, helium fills a balloon to 1.00 L. What would the pressure be if the volume of the balloon stretched to 2.00 L? Formula: P 1 V 1 = P 2 V 2 P 2 = P 1 V 1 /V 2 P 2 = (0.988 atm)x(1.00 L)/(2.00 L) P 2 = 0.494 atm
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STP Standard Temperature and Pressure Temperature: 0 °C (32 °F or 273 Kelvin) Pressure: 1 atm (101.325 kPa, 14.7 PSI, 760 mmHg, or 760 Torr).kPaPSI
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