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Chapter 8 Chemical Reactions
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8-1 Nature of Chem Rxn’s *form a new substance
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-Characteristics of chem rxn’s *reactants: substance that enters into a chem rxn *products: substance being produced by the rxn
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-Characteristics of chem rxn’s -reactants yields products -involve a change in nrg as well -nrg is either absorbed or released
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-Capacity to React -determined by the arrangement of valence e-’s
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8-2 Chemical Equations -involves the rearrangements of atoms *expression in which symbols and formulas are used to represent a chem rxn -reactants yields products
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Conservation of mass -atoms can be neither created nor destroyed during a chem rxn
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-Conservation of mass -if the # of atoms remains the same, then the mass must remain the same *Law of conservation of mass: mass remains constant in a chem rxn
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-Balancing Chem *# of atoms of each element is the same on both sides of the equation *Coefficients: #’s that indicate how many atoms or molecules of each substance
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-Balancing Chem Ex: -remember to balance a chem equation you can change coeff but never symbols or formulas
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-Balancing Chem -steps: 1. Write the chem equat(look for diatomics)
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-Balancing Chem 2. Write down the oxidation #’s 3. Make oxidation #’s = 0 4. Balance left and right side
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8-3 Types of Chem Rxn’s -synthesis, decomposition, single replacement, and double replacement…. and Combustion
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-Synthesis Rxn *two simple substances form a more complex substance EX: corrosion of metals
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-Decomposition Rxn *complex substance breaks down into two or more simpler substances Ex
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-Single-replacement rxn’s *an uncombined element replaces an element that is part of a cmpnd EX:
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-Double-Replacement Rxn *different atoms in two different cmpnds replace eachother -2 cmpnds react to form 2 new cmpnds EX:
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Combustion _____ + O 2 ----> CO 2 + H 2 O
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8-4 Energy of Chem Rxn’s -chem rxn = change in nrg -nrg is never created or destroyed in chem rxn’s -Two types of chem rxn’s
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1. Exothermic Rxn *nrg is released -Ex: combustion -nrg of product is less than the nrg of the reactant - Equation: R -----> P + nrg
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2. Endothermic Rxn’s *nrg is absorbed -nrg of the products is more than the nrg of the reactants -Equation: R + nrg ----> P
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-Activation Energy *nrg needed to start a rxn -form short-lived, high nrg, extremely unstable molecule -all chem rxn’s require activation nrg -nrg diagrams:
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8-5 Rates of Chem Rxn *Kinetics: study of rxn rates *Rxn rates: how quickly reactants turn into products
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-Collision Theory *relates molecular coll to rxn rate -reacting molecules must collide with sufficient nrg
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-Rates of rxn are determined by the following: 1. Concentration 2. Surface area 3. Temp 4. Catalysts
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1.Concentration *measure of the amount of that subst in a given unit of vol. -high conc. = many particles per vol -usually if you increase the conc of reactants you increase the rate of the rxn
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2. Surface Area -increase in surface area increases the collision between reacting molecules
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3. Temperature -increase in temp generally increases the rate of rxn
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3. Temperature *Temp: measure of the nrg of their motion -at room temp, the rates of many chem rxn’s 2bl or 3pl with a rise in temp of 10 degrees C
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4. Catalysts *substance that increases the rate of rxn but is not itself changed by the rxn -reduces the activation nrg required to start a chem rxn
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