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!Electrons in Atoms Chapter 13.1 and 13.2
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Atomic Models !Atomic models help explain the nature of elements—part of atomic theory We can not see atoms, so how do we know they exist?
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!Scanning Tunneling Microscope
!Can “see” atoms! Can even be used to rearrange individual atoms!
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!Thompson’s Plum Pudding Model
Thompson imagined a positively charged ball of “pudding” with electrons (which he discovered) as the “plums” inside
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Niels Bohr’s Model 1913: !Bohr imagined electrons follow circular orbits around the nucleus, like a solar system
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Energy Levels !The energy level of an electron is the region around the nucleus where the electron is moving
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!Energy Levels are Fixed
!Energy levels are like rungs on a ladder !Electrons exist on rungs !Electrons can jump between rungs !Electrons can’t exist between rungs
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It takes energy to jump between energy levels
!Quantum: The amount of energy required to move from one energy level to another Part of the Quantum Theory
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Neils Bohr "If quantum mechanics hasn't profoundly shocked you, you haven't understood it yet."
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Light and Atomic Spectra
!Spectrum: a series of energies (like light) arranged according to wavelength, or frequency
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!Atomic Emission Spectrum
!Every element (vapor) emits light when it is excited by the passage of electric discharge.
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Atomic Emission Spectrum
!Passing this light through a prism creates a spectrum, different for every element. !Each line represents one exact amount of energy
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More on Quantum Theory:
Subatomic particles don’t follow the rules of classical physics Gravity doesn’t apply! Time doesn’t apply! Can move without occupying space! Superposition—can’t locate position! Order of operations don’t always apply!
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Neils Bohr "If quantum mechanics hasn't profoundly shocked you, you haven't understood it yet."
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The Quantum Mechanical Model
Erwin Schrodinger, in 1926, used quantum theories to solve a mathematical equation concerning the location and energy of an electron. (But not both at once)
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!Electron Orbitals—Quantum Theory
!The area where an electron is likely to be found. (90% chance) !An orbital can contain two electrons.
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Energy levels and orbitals
!Types of orbitals !s orbital = sphere shaped (1 type) !p orbitals = dumbell shaped (3 types) !d orbitals = clover shaped (5 types)
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Electron Configurations
High energy = unstable, higher energy levels, further away from nucleus Low energy = stable Three major rules tell you how to find where electrons will be:
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!Rule 1: Aufbau Principle
!Electrons enter orbitals of lowest energy first.
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!Rule 2: Pauli Exclusion Principle
!An atomic orbital is one or two electrons To be in the same orbital, two electrons must be “opposite”
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!Rule 3: Hund’s Rule !Electrons in the same energy level must enter each orbital until all the orbitals contain one electron with parallel spins.
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!Electron Cloud !All the electrons in all the orbitals.
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