Download presentation
Presentation is loading. Please wait.
Published byNeal Park Modified over 9 years ago
1
V6543210V6543210
2
V6543210V6543210
3
The wavefunctions of the Simple Harmonic Oscillator are Orthonormal
4
Orthonormal wavefunctions
5
∫ + ∞ - ∞ ψ v ” ψ v ’ dτ = δ v ” v ’ Orthonormal wavefunctions
6
∫ + ∞ - ∞ ψ v ” ψ v ’ dτ = δ v ” v ’ Orthonormal wavefunctions Kronecker delta δ ij = 1 when i = j and 0 when i ≠ j
7
+ + ∫ + ∞ - ∞ ψ v=0 ψ v =0 dτ = 0 Orthonormal wavefunctions ← – ∞ + ∞ →
8
V6543210V6543210
9
+ – ∫ + ∞ - ∞ ψ v=1 ψ v =0 dτ = 0 Orthonormal wavefunctions ← – ∞ + ∞ →
10
V6543210V6543210
11
+ + – ∫ + ∞ - ∞ ψ v=2 ψ v =0 dτ = 0 Orthogonal wavefunctions ← – ∞ + ∞ →
12
Anharmonic oscillator wavefunctions and probabilities
19
V6543210V6543210
21
x → -8 -6 -4 -2 0 2 4 6 8 12 10 8 6 4 2 0 y = x 2
23
x → ↑y↑y -8 -6 -4 -2 0 2 4 6 8 12 10 8 6 4 2 0 y = x 2
24
x → ↑y↑y -8 -6 -4 -2 0 2 4 6 8 12 10 8 6 4 2 0 y = x 2
25
x → ↑y↑y -8 -6 -4 -2 0 2 4 6 8 12 10 8 6 4 2 0 y = x 2
26
x → -8 -6 -4 -2 0 2 4 6 8 12 10 8 6 4 2 0 y = x 2
27
x → -8 -6 -4 -2 0 2 4 6 8 12 10 8 6 4 2 0 y = x 2
28
x → -8 -6 -4 -2 0 2 4 6 8 12 10 8 6 4 2 0 y = x 2
29
x → -8 -6 -4 -2 0 2 4 6 8 12 10 8 6 4 2 0 y = x 2
30
x → -8 -6 -4 -2 0 2 4 6 8 12 10 8 6 4 2 0 y = x 2
31
x → -8 -6 -4 -2 0 2 4 6 8 12 10 8 6 4 2 0 y = x 2
32
x → ↑y↑y -8 -6 -4 -2 0 2 4 6 8 12 10 8 6 4 2 0 y = x 2
34
x → ↑y↑y -8 -6 -4 -2 0 2 4 6 8 12 10 8 6 4 2 0 y = x 2
35
x → -8 -6 -4 -2 0 2 4 6 8 12 10 8 6 4 2 0 y = x 2
36
x → -8 -6 -4 -2 0 2 4 6 8 12 10 8 6 4 2 0 y = x 2
37
x → ↑y↑y -8 -6 -4 -2 0 2 4 6 8 12 10 8 6 4 2 0 y = x 2
38
x → -8 -6 -4 -2 0 2 4 6 8 12 10 8 6 4 2 0 y = x 2
39
x → -8 -6 -4 -2 0 2 4 6 8 12 10 8 6 4 2 0 y = x 2
40
x → ↑y↑y -8 -6 -4 -2 0 2 4 6 8 12 10 8 6 4 2 0 y = x 2
41
x → ↑y↑y -8 -6 -4 -2 0 2 4 6 8 12 10 8 6 4 2 0 y = x 2
42
x → -8 -6 -4 -2 0 2 4 6 8 12 10 8 6 4 2 0 y = x 2
43
x → -8 -6 -4 -2 0 2 4 6 8 12 10 8 6 4 2 0 y = x 2
44
x → -8 -6 -4 -2 0 2 4 6 8 12 10 8 6 4 2 0 y = x 2
45
x → -8 -6 -4 -2 0 2 4 6 8 12 10 8 6 4 2 0 y = x 2
46
x → ↑y↑y -8 -6 -4 -2 0 2 4 6 8 12 10 8 6 4 2 0 y = x 2
47
http://en.wikipedia.org/wiki/File:Simple_harmonic_oscillator.gif
48
H + H E(r) r 0 Rotational levels Continuum wavefunction of a dissociating state
49
http://131.104.156.23/Lectures/CHEM_207/uv-vis.htm
51
http://hyperphysics.phy-astr.gsu.edu/hbase/quantum/hosc5.html
57
H + H r E(r) The problem of how to make H 2 in Space H2H2
62
http://jchemed.chem.wisc.edu/JCEDLib/SymMath/collection/article.php?id=29
63
http://www.pci.tu-bs.de/aggericke/PC3e_osv/Kap_III/Molekuelschwingungen.htm
Similar presentations
© 2025 SlidePlayer.com. Inc.
All rights reserved.