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Published byPaul Arron Stevenson Modified over 9 years ago
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Covalent Compounds Chapter 6 6-1 Covalent Bonds
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Covalent Bond The sharing of electrons between atoms Forms a molecule To have stable (filled) orbitals
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Diatomic Molecules Formed by covalent bond between two atoms of the same element
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Molecular Orbital The space in which the shared electrons move
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Energy and Stability Un-bonded atoms (except noble gases) have low stability and high potential energy Energy is released when they form a bond
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Attraction and Repulsion When balanced, a covalent bond forms
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Bond Length The distance between two bonded atoms at their minimum potential energy
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Bond Energy The energy required to break a bond kJ/mol
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Electronegativity and Covalent Bonding Electronegativity - How much an atom attracts electrons Atoms share electrons equally or unequally – depending on the electronegativity of the atoms
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Nonpolar Covalent Bonds Electrons are shared equally
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Polar Covalent Bonds Atoms share electrons unequally Have different electronegativities
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Dipole Molecule One end is partial positive and the other end is partial negative Hydrogen and fluorine
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Polarity and Bond Strength The greater the difference in electronegativity, the greater the polarity, and the greater the bond strength ------------------ Bond Strength ------------------
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Determining Bond Types Differences in Electronegativity of the atoms
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Metallic Bonds Results from the attraction between metal atoms and the surrounding sea of electrons
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Properties of Substances Depends on Bond Type Metallic – good conductors Ionic – strong bonds, high melting point See table 3 page 197
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Drawing and Naming Molecules Section 6-2
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Valence Electrons
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Lewis Electron- Dot Structure s
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Octet Rule
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Lewis Structures Model Covalently Bonded Molecules
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Unshared (lone) Pairs Not part of the bond
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Single Bond The shared pair Can be shown by a dash
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Lewis Structures for Polyatomic ions Ammonia Ammonium ion enclose in brackets w/ + charge
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Double Bonds Share 4 (2 pair) electrons Carbon, oxygen, nitrogen
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Triple Bonds Share 6 (3 pair) electrons Nitrogen and Carbon
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Naming Covalent Compounds Similar to Ionic bonds -ide suffix Prefixes indicating number On first element, only if more than one
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Molecular Shapes Section 3
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Determining Molecular Shapes The shape helps determine the molecules physical and chemical properties
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Linear Shape “In a line” Molecules made of 2 atoms H 2 or CO
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VSEPR Theory Pronounced “vesper” A model used to predict the shape of a molecule Valence Shell Electron Pair Repulsion Theory Based on the idea that valence electrons repel each other
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Linear Shape The shared pairs repel each other and remain as far apart as possible
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Bent Shape Water H 2 O Two shared pairs and two unshared pairs The unshared pairs influence the shape
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Tetrahedral Methane CH 4 Four shared pairs
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Trigonal Planer BF 3 CH 2 O (Formaldehyde) 3 shared pairs Maximum distance apart
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Trigonal Pyramidal 3 bonding pairs, 1 lone pair Ammonia NH 3
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Molecular Shapes Affects a Substance’s Properties Shape affects Polarity
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Polarity affects Properties
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