1. HBr, https://notendur.hi.is/~agust/rannsoknir/Crete/PPT-140707.pptx Potential curve diagram for HBr and HBr + (See next slides):

2. [ 4 ,5s] Rydb. H + Br**(5s) H*(n=2)+Br H + + Br - H+Br + + e H + +Br+e [B 2   ].. superexcited state [(3) 2  ].. superexcited state HBr + *(A) HBr + (X(3/2)) Photoexcitation via V(m+7) https://notendur.hi.is/~agust/rannsoknir/Crete/PXP-131203.pxp V F H HBr +* (X(1/2)) v + =14 v + =12 E H + Br** H * +Br

3. Fig. 5 in manuscript

4. Gabriel Vazquez; private communication

5. See next slide cm-1

6. 30000 40000 60000 50000 H + Br + ( 3 P 2 ) H + Br + ( 3 P 1 ) H + Br + ( 3 P 0 ) 3136.4 cm-1 NIST H + Br + ( 1 D 2 ) H+ + Br ( 2 P 3/2 ) H+ + Br ( 2 P 1/2 ) 3685.24 NIST