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Bonding Ionic versus Covalent
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Ionic Bonding What is it? Bonding between a metal and a non metal What holds the bonds together? Electrostatic attraction between (+) and (-) “charges” which results from the transfer of the electrons from the least e-neg (metal) to the most e-neg (nonmetal)
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What happens to the electrons? One gets (-) the other gives (+). Each resulting ion resembles a noble gas. The (-) resembles the noble gas in the same period. The (+) resembles the noble gas from the period above.
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Types of compounds Formula unit a single piece of the crystal lattice or ionic compound. Conductivity Conducts electricity when molten or dissolved in solution. (When ions can move around they can conduct the electric charge)
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Electronegativity Large electronegativity differences – greater than 50% or about 1.7 and greater State of Matter Solids with a very strong bond
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Other characteristics Ions: elements or group of elements that have a “charge” from an imbalance in + and – Lewis Dot Structure The most e- neg element gets all the electrons show with arrow for e-transfer and ion charge created.
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Covalent Bonding
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What is it?: Nonmetal + nonmetal What holds the bonds together? Attraction between nuclei of bonding atoms and e- Intermolecular forces: affect the bond polarity and molecular polarity London Dispersion-induced dipole Dipole-dipole Hydrogen bonding Nonpolar: London disp. Only Polar: London disp. And dip-dip with FON to H, hydrogen bonding
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What happens to the electrons? The atoms share electrons to look like a noble gas. Nonpolar bonds share electrons evenly. Polar bonds share unevenly depending on electronegativity. What types of compounds? Molecule is single “piece” of a molecular compound.
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Conductivity? Does not conduct (no ions – no conduction) Electronegativity? Little electronegativity difference. Nonpolar = less than 0.4 difference. Polar = greater than 0.4 but less than 1.7
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States of Matter: All 3 states. Weaker bond: state depends on size of molecule and intermolecular forces. Stronger than ionic bonds. Other: Multiple bonds: C.SON group forms a double, triple bonds. Diatomic molecules: 2 atoms same element bonded together. BrINClHOF
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Shapes: VSEPR Valence shell electron repulsion theory – shapes based on shared and lone pair electrons and central atom. Formulas Oxidation State: Find normal charge
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Lewis Dot Structure for Covalent Molecules Why: Show how the valence electrons are arranged. Use one dot to represent each valence electron. A stable compound has all its atoms with a noble gas configuration. (8 v.e.) Hydrogen follows the duet rule. (2 v.e.) The rest of the elements follow the octet rule. Bonding pair is the one between the symbols.
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How Sum the valence electrons. Draw skeletal structure. Central atom is carbon (if present) or the least electronegative atom Use a pair of electrons to form a single bond between each pair of atoms. Arrange the rest to fulfill the octet rule (except for H and the duet).
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