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Organic Chemistry Branch of chemistry dealing with carbon molecules.
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Hydrocarbons Compounds containing only carbon & hydrogen
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Why can carbon form so many compounds? It can form up to 4 covalent bonds with other carbon atoms.
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What is the maximum # of bonds between any 2 C atoms? A triple bond (3 pairs or 6 electrons)
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Properties of hydrocarbon molecules Molecular Low melting points Low boiling points Low H f Low H v High evaporation rate High vapor pressure May be gases, liquids, or solids Decompose on heating Poor conductors of heat & electricity Nonpolar (vdw forces) Dissolve in nonpolar solvents React slowly Solids may be soft or brittle
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Bonding capacity of H? 1
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Bonding capacity of O? 2
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Bonding capacity of the halogens (F, Cl, Br, I)? 1
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Bonding capacity of S? 2
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Bonding capacity of N & P? 3
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Bonding capacity of C? 4
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The 4 single bonds of a carbon atom are directed to … the corners of a regular tetrahedron.
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Saturated hydrocarbon Hydrocarbon containing only single carbon-carbon bonds
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Unsaturated hydrocarbon Hydrocarbon containing at least 1 double or triple carbon-carbon bond
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Chemical or Molecular Formulas Tell the kind & number of atoms in a molecule.
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Structural Formulas Tell the kind & number of atoms in a molecule. Also attempt to show approximate shapes & bonding patterns of molecules.
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Homologous Series A group of related compounds in which each member differs from the one before it by the same additional unit. Properties vary in a predictable way.
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Alkanes Homologous series of saturated hydrocarbons. with the general formula C n H 2n+2. Ratio of C to H is n:2n+2
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Alkanes Release energy when burned: fuels.
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Naming Alkanes Prefix: depends on # of carbon atoms in longest continuous chain. Suffix: ane
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Properties of Alkanes Nonpolar. Boiling point as # of carbon atoms . (van der Waals forces increase with size). Insoluble in water. (Like dissolves like.)
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Nonpolar The electron cloud of the molecule is fairly evenly distributed. Either: –Molecule has atoms with similar electronegativities –Molecule has high symmetry
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Isomers Molecules with the same chemical formula but different structural formulas. Different chemical & physical properties. Different names. Same formula mass & percentage composition.
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Isomers # of possible isomers as # of C atoms
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Alkenes Homologous series of unsaturated hydrocarbons containing 1 double carbon- carbon bond.
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General formula of alkenes C n H 2n
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Naming Alkenes Prefix: depends on # of carbon atoms in longest continuous chain. Suffix: ene # in front may give location of double bond.
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Properties of Alkenes Slightly more reactive than the alkanes. Double bond is site of reactivity.
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Alkynes Homologous series of unsaturated hydrocarbons containing 1 carbon-carbon triple bond.
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General formula of alkynes C n H 2n-2
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Naming alkynes Prefix: depends on # of carbon atoms in longest continuous chain. Suffix: yne # in front gives location of triple bond.
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