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Published byToby Carter Modified over 9 years ago
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Alkanes & Alkenes Definition & Naming Heuristics (Mnemonics)
Physical & Chemical Properties General & Structural Formula
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Definition of HOMOLOGOUS SERIES
A group of organic compounds with the SAME general formula, in which one member differ from the next by a –CH2 group.
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Heuristics Mummy Eats Peanut Butter Pancake Happily 1 Met- 2 Eth- 3
No. of carbon atoms Mnemonic Chemical Formula 1 Mummy Met- 2 Eats Eth- 3 Peanut Prop- 4 Butter But- 5 Pancake Pent- 6 Happily Hex-
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Diagrammatic representation
Mummy Eats Peanut Butter Pancake Happily
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when drawing structural formula,
Guiding principles when drawing structural formula, Symbol Name of element Number of lines H Hydrogen 1 O Oxygen 2 N Nitrogen 3 C Carbon 4
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CH4 C2H6 C3H8 Naming of Alkanes General Formula : CnH2n+2 H H-C-H H H
No. of carbon atoms Name Chemical Formula Structural H H-C-H H H H-C-C-H H H H H-C-C-C-H CH4 1 Methane C2H6 2 Ethane C3H8 3 Propane
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C4H10 C5H12 C6H14 Naming of Alkanes H H H H H-C-C-C-C-H H H H H H
No. of carbon atoms Name Chemical Formula Structural H H H H H-C-C-C-C-H H H H H H H-C-C-C-C-C-H H H H H H H H-C-C-C-C-C-C-H C4H10 4 Butane C5H12 5 Pentane 6 C6H14 Hexane
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C2H4 C3H6 Naming of Alkenes General Formula : CnH2n H H H-C=C-H 1
No. of carbon atoms Name Chemical Formula Structural - H H H-C=C-H H H H H-C=C-C-H H 1 C2H4 2 Ethene C3H6 3 Propene
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C4H8 C5H10 C6H12 Naming of Alkenes H H H H H-C=C-C-C-H H H H H H H H
No. of carbon atoms Name Chemical Formula Structural H H H H H-C=C-C-C-H H H H H H H H H-C=C-C-C-C-H H H H H H H H H H H-C=C-C-C-C-C-H H H H H C4H8 4 Butane C5H10 5 Pentane 6 C6H12 Hexane
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Physical Properties for straight-chain alkanes
Boiling pt as the number of carbon atoms . Boiling point Number of carbon atoms
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Chemical Properties for straight-chain alkanes
Generally unreactive except with oxygen. Alkane + oxygen carbon dioxide + water C2H O CO H2O
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Chemical Properties for straight-chain alkenes
Reaction with oxygen. Alkene + oxygen carbon dioxide + water C2H O CO H2O Reaction with hydrogen. Alkene + hydrogen Alkane C2H H C2H6
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Chemical Properties for straight-chain alkenes
Reaction with steam. Alkene + steam Alcohol C2H H2O C2H5OH Phosphoric (V) acid catalyst Reaction with bromine. Alkene + bromine ,2-dibromoalkane C2H Br C2H4Br2 colourless orange-red
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