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Redox Neutral Reactions Wang Chao 2011.3.12
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Redox Economy and Redox Neutral Reactions: Angew. Chem. Int. Ed. 2009, 48, 2854 – 2867
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Developed by Noyori; Employed by Takasago in total synthesis of Menthol
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Scheidt: J. AM. CHEM. SOC. 2009, 131, 18028–18029
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Hydride Shift Reactions: transition metals, lewis acids, organocatalysis Akiyama:J. Am. Chem. Soc. 2011, 133, 2424–2426 Seidel:J. Am. Chem. Soc. 2011, 133, 2100–2103 recent examples:
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Borrowing Hydrogen: reduction and oxidation coupled Adv. Synth. Catal. 2007, 349, 1555 – 1575
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Breit: J. Am. Chem. Soc. 2011, 133, 2386–2389
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Transition metal mediated dehydrogenative activation Chem. Rev. 2010, 110, 681–703
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N-Alkylation of Amines by Alcohols: Alkylation of Activated Nucleophiles by Alcohols:
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Krische: Angew. Chem. Int. Ed. 2009, 48, 34–46 J. Am. Chem. Soc. 2007, 129, 15134. Angew. Chem., Int. Ed. 2008, 47, 5220. J. Am. Chem. Soc. 2008, 130, 14891. Transfer Hydrogenative C-C Coupling:
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Hydroacylation:
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Mechanism of activation of alcohol:
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