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Ions and Ionic Compounds
Chapter 5 5-1 Simple Ions
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Valence Electrons Electrons in the outer energy level
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The Octet Rule
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Valence electrons and the Periodic Table
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Chemical Reactivity How reactive an element is
Depends on the electron configuration Notice the Noble gases
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Noble Gases Filled s and p sublevels ns2 np6 Least Reactive elements
Filled outer energy levels Noble Gases Filled s and p sublevels ns2 np6
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Alkali Metals and Halogens
The most reactive elements Alkali Metals, 1 valence electron Halogens, seven valence electrons
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Lewis Dot Diagram Lewis Dot, or Electron Dot Diagram
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Ions Atoms Gain or Lose Electrons to Form Stable Ions
(Have the same electron configuration of a noble gas)
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Characteristics of Stable Ions
Some Ions have noble gas configurations, but are not like noble gases Ions have a charge and so they form compounds Noble gases are very unreactive
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Some stable Ions do NOT have noble gas configurations
Mainly the transition metals Lose valence electrons Some form more than 1 stable ion
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Ions have different properties from parent atoms
Sodium and Chlorine are both dangerous But the ions together make table salt
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Ions from metals and non-metals
Form cations (positive) Form anions (negative)
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Ionic Bonding and Salts
5-2
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Ionic Bonding Electrons are transferred Ionic Compound
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Ionic Bonding Ionic Bonds form between ions of opposite charge
Forms Salts
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Ionic bonds from between metals and non-metals
Form cations (positive) Form anions (negative)
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Transferring electrons involves energy change
Removing an electron requires energy (ionization energy) Adding an electron releases energy (electron affinity)
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Ionic Bonding and Energy
The net result of ionic bond formation is the release of energy (exothermic) Called Lattice Energy
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Lattice Energy A measure of the strength of an ionic bond
The greater the lattice energy, the stronger the bond
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Salt Crystals The ions in a salt form a repeating pattern called a crystal lattice The smallest repeating unit is called a unit cell
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Ionic Compounds Do not consist of molecules
Each cation is surrounded by 6 anions and vise versa
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Ionic Compound Crystals
In a ratio that results in the compound having no charge (electroneutral)
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Ionic Bonds are Strong Stronger than molecular (covalent) bonds (like water) Takes more energy to break them Results in high melting and boiling points
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Names and Formulas of Ionic Compounds
Section 5-3
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Ionic bonds from between metals and non-metals
Form cations (positive) Form anions (negative)
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Writing Ionic Formulas
Ionic compounds are always electroneutral The formula for the compound is written thusly
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Rules for Naming Simple (monatomic) Ions
Naming the cation The name of the cation is the name of the element Sodium atom makes a sodium ion Some elements (transition metals) have more than 1 ion Use roman numerals to indicate the charge Copper (II) ion or Copper (I) ion have charge of Cu+2 or Cu+ Iron (II) ion or Iron (III) ion
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Naming simple ionic compounds
The cation followed by the anion with –ide on the end
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Naming Ionic Compounds
Say the names of these compounds
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Polyatomic Ions A charged group of two or more bonded atoms Hydroxide
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Names of Polyatomic Ions
The endings –ite and –ate indicate oxygen If more than one, -ite is the lesser and –ate is more oxygen
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Presence of Hydrogen Name starts with hydrogen Prefixes mono- and di-
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Naming Compounds with Polyatomic Ions
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