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Published byGary Oliver Modified over 9 years ago
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Photochemistry can be dramatically different from “ordinary” chemistry See example below
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Ar Cl
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Ar Cl...
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Ar
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Cl Ar + -
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Cl Ar
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O3 O3O3 Cl Hvernig er efnafræði ósoneyðingar- innar?/ Ozon depletion?
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( ) 20 km ( )
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Heildarloftstyrkur og ósonstyrkur yfir jörðu. / Concentration profiles for air and ozone in the Earth´s atmosphere.
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20 km
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Gleypni ósons á nær-útfjólubláa litrófssviðinu. Gleypnistuðull er í réttu hlutfalli við gleypni efnisins fyrir fastann efnisstyrk. Absorption cross section of ozone in the near UV spectral region.
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20 km
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20 km O 3 + O -> O 2 +O 2
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Chemistry and spectroscopy of the greenhouse effect/ Global warming effects(?)
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Gegnskin og gleypni andrúmsloftsins ÚF SÝNSÝN....................................IR...............................
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Bylgjulengd ( m) Gleypni O=C=OO=C=O
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UltravioletVisibleNear-IRInfraredFar-InfraredMicrowave
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Organic photochemistry: photoisomerization
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Stilben e(1)
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Stilbene(2)
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Astrochemistry
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C2H2C2H2 Big organic molecules : Life(?) ???
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C2H2C2H2 Big organic molecules : Life(?) ???
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C2H2C2H2 Big organic molecules : Life(?) ??? C2C2 C CH 2
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H+H+ CH + CH 2 + C+C+ C2+C2+ C2H+C2H+ C2H2+C2H2+ Magn jóna Ion yield LASER radiation of C 2 H 2 Mw Time of flight
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Orka HCCH: HCCH*:
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Orka C2C2 H2H2 HCCH*: C2C2 + +
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Orka HCCH*:
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Orka HCCH*: CH 2 C
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A + M ??? M 1 + M 2 ??? A + B C + D Reaction cross section:
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A + M ??? M 1 + M 2 ??? A + B C + D Cross section = = 2 d But ions: Reaction cross section:
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A + + B C + D But ions: ++ - - - - + + + + F 1/r 2 Reaction cross section:
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+ A + + B C + D But Ions: + - - - - + + + + Reaction cross section:
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A + + B C + D But ions: ++ Collision frequency much larger Reaction cross section:
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A + M ??? M 1 + M 2 ??? A + B C + D d + Ions: Collision cross section = >> 2 Reaction cross section:
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