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Test 7: Chemical Bonding
Cartoon courtesy of NearingZero.net
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Octet Rule Octet Rule: Atoms will gain, lose, or share valence electrons with other atoms in order to obtain an octet (8 valence electrons). Exceptions: Hydrogen & Helium – only 2 valence electrons because the 1st PEL holds 2 electrons In other words, a stable electron configuration.
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Ions Recall: Atoms are neutral. Why?
An ion is the charged particle formed when a neutral atom loses or gains electrons. If an atom gains electrons, it becomes a NEGATIVELY charged ion. If an atom loses electrons, it becomes a POSITIVELY charged ion.
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Metal Ions Metals tend to lose electrons and form smaller sized ions that are positively charged. Atom Ion
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Nonmetal Ions Nonmetals tend to gain electrons and form larger sized ions that are negatively charged. Atom Ion
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Why? Metals generally have 1, 2, or 3 valence electrons. For metals it is easier to lose those than gain 5,6,or 7 additional electrons. Nonmetals generally have 5, 6, or 7 valence electrons. For nonmetals it is easier to gain 1, 2, or 3 more electrons than to lose 5, 6, or 7 electrons. They want the electron configuration of the Noble Gas closest to their atomic number.
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Ion Charges Possible ion charges are listed as oxidation numbers on the PT Example: aluminum ion = 3+ oxygen ion = 2- chloride ion = 1-
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Bonding Chemical bonds are attractive forces that hold atoms together.
2. Compounds – 2 or more different atoms chemically bonded together ex: NaCl or H2O 3. Diatomic Elements – 2 of the same atoms bonded together ex: H2 O2 F2 Br2 I2 N2 Cl2
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Hey! I find your electrons attractive!
Electronegativity (attraction for another atom’s electrons) Get lost, loser! Hey! I find your electrons attractive!
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Electronegativity – Table S
Metals – Low #’s Nonmetals – Big #’s low attraction big attraction Think Metals lose e- & form + ions Nonmetals gain e- & form - ions
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(less than 1.7 but more than zero)
Chart to Memorize! Type of Bond Ionic Polar Covalent Nonpolar Covalent Electronegativity Difference… >1.7 (equal to or more than 1.7) 1.7>x>0 (less than 1.7 but more than zero) = zero Valence Electrons are… Transferred Shared unequally Shared Equally How to Recognize… Metal & Nonmetal 2 Different Nonmetals 2 of the same Nonmetals Chemical Formula for one example… NaCl H2O H2
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Electronegativity Chart
To Determine Electronegativity Difference for CaBr2: Br = 3.0 Ca = 1.3 Difference is 1.7 So CaBr2 Bond is Ionic
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