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WOOD 120 Pulp and Paper
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Raw material Paper products
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Chemical pulp mill
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Chemical pulp mill
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Composition of Paper Surface Section through paper sheet
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Lignin “glues” wood cells together
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fibers or fiber bundles
wood
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Pulping Mechanical Uses heat and mechanical energy Higher yield
Lower quality Chemical Uses heat and chemical energy Lower yield Higher quality
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World Pulp Production (2012) (x106 metric tonnes)
Recovered paper Mechanical pulp Full chemical pulp Kraft Sulphite Dissolving pulp Non-wood fiber pulp
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Raw material – wood supply
Logs Chips
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Pulp and Paper – overview of production stages
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Pulping
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Pulp treatment
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Papermaking
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Mechanical pulping fibers or fiber bundles wood
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Stone ground wood Refiner pulps
Mechanical Pulping Stone ground wood Refiner pulps
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Debarking Drum debarkers
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Stone Ground Wood bolts of wood hydraulic pistons grinding stone
pulp slurry
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Stone Ground Wood
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Stone Ground Wood Raw material – short logs (bolts) High yield
Low quality fibers or fiber bundles High energy input Pulp suitable for tissues
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Refiner pulping
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Pretreatment of chips
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Refiner pulping http://www.globalequip.com/photos/bg_901371.001_2.jpg
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Multiple refiners in parallel
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Refiner pulping Raw material – chips Lower yield than SGW
Medium quality fibers or fiber bundles High energy input Pulp suitable for newsprint
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The “Alphabet Pulps” RMP refiner mechanical pulp
TMP thermo mechanical pulp CTMP chemi thermo mechancial pulp SGW stone ground wood PGW pressurized ground wood NSSC neutral sulfite semi chemical
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Chemical pulping wood individual fibers
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Sulfate process (Kraft) Sulfite process
Chemical Pulping Sulfate process (Kraft) Sulfite process
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Kraft process Delignifies wood by
fragmenting lignin into smaller units adding chemical groups to increase the lignin’s solubility Tolerates wide range of species High strength pulp Lower yield than mechanical pulps
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Kraft digester - continuous
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Kraft pulping – continuous digester
Chips and pulping chemicals Steam Blow valve Gases Pulp
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Kraft liquor recovery cycle
Wood Pulping Pulp White liquor Washing Bleaching Evaporation Cauticising Bailing & Shipping Black liquor Green liquor Burning Green liquor recovery cycle
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Bleaching / Brightening Beating (refining)
Pulp treatment Bleaching / Brightening Beating (refining)
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Pulp and Paper – overview of production stages
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Raw material Paper products
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Bleaching vs. Brightening
Continuation of pulping process Removal of residual lignin left after pulping More permanent Applied to chemical pulps Brightening Distinct from pulping process Impact chromophoric structures in lignin More temporary Applied to mechanical pulps
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Bleaching/brightening chemicals
C chlorine Cl2 D chlorine dioxide ClO2 O oxygen O2 Z ozone O3 P peroxide H2O2 E alkaline extraction NaOH
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Bleaching/brightening sequences
Classic e.g., C E D E D Elemental Chlorine Free (ECF) e.g., D E D E D Totally Chlorine Free (TCF) e.g., O Z E P
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Bleaching Towers
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Pulp Beating Flattens fibers to produce larger surface area – increases hydrogen bonding between fibers Unravels fibers to some degree Optimum beating time to achieve best paper properties
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Pulp Beating Jordan refiner
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Pulp Beating After beating Before beating
Internal and external defibrillation take place
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Papermaking Foudrinier machine - thinner paper sheet - faster production speed Cylinder machine - thicker paper sheet - slower production speed
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Papermaking Foudrinier machine - thinner paper sheet - faster production speed
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Foudrinier papermaking machine
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Foudrinier - schematic
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Blending of pulp stocks
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Foudrinier papermaking machine
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Foudrinier – wet-end
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Foudrinier – wet-end
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Foudrinier - presses
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Foudrinier – dry-end
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Foudrinier – calendering and winding
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Foudrinier – moisture loss in paper
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Papermaking Cylinder machine - thicker paper sheet - slower production speed
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Cylinder papermaking machine
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Cylinder papermaking machine
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Schematic of cylinder machine
Couch roll Paper layer forms on screen Level of pulp stock vacuum pressure Fibres in suspension Screen rotates Mold remains fixed
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Cylinder papermaking machine
Dryers
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World Paper Production (2012) (x106 metric tonnes)
Wrapping, packaging and board Coated paper Newsprint
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