1. Monitoring PCDD & PCDF Sampling in stack Quim. Marcelo Souza dos Anjos ipaa_cetesb@sp.gov.br

2. Monitoring PCDD& PCDF Sampling in stack in São Paulo 1985 - Installed the first incinerator 1987 - first Test of Burn The 90 other incinerators are installed in the State of São Paulo in 1996 - the first test for evaluation of dioxins and furans because of licensing requests receipt of PCBs in one of four permitted incinerators to burn waste from third parties

3. Monitoring PCDD & PCDF Since 2005, because of new national legislation, incinerators, furnaces and boilers and coprocessing using waste for energy recovery or thermal destruction should monitoring dioxins and furans at least every 02 years Annual monitoring may be required depending on the location and characteristics of waste Monitoring of particulate matter every 06 months or 01 years

4. Monitoring PCDD & PCDF USEPA Method 23 03 sample by source Obligation to hold a blank field for sample Minimum sample volume of 2.7 Nm3 Sample equipment shall be of PTFE / Glass

5. Toxicity Equivalency Factors-FTEQ from 2,3,7,8 TCDD DioxinaUSEPA 2,3,7,8 – TCDD1.0 1,2,3,7,8 – PeCDD0.5 1,2,3,4,7,8 – HxCDD0.1 1,2,3,6,7,8 – HxCDD0.1 1,2,3,7,8,9 – HxCDD0.1 1,2,3,4,6,7,8 – HpCDD0.01 OCDD0.001 FuranoUSEPA 2,3,7,8 – TCDF0.1 1,2,3,7,8 – PeCDF0.05 2,3,4,7,8 – PeCDF0.5 1,2,3,4,7,8 – HxCDF0.1 1,2,3,6,7,8 – HxCDF0.1 1,2,3,7,8,9 – HxCDF0.1 2,3,4,6,7,8 – HxCDF0.1 1,2,3,4,6,7,8 – HpCDF0.01 1,2,3,4,7,8,9 – HpCDF0.01 OCDF0.001

6. 6 Method of stack sampling CompoundBoiling Point(°C) Particulate>300 Semi-Vost120 a 300 Vost30 a 120

7. New POPSCAS Chemical Form Boiling Point (C°) Chlordecone143-50-0C 10 Cl 10 O434 Haxabromobiphenyl36355-01-8C 12 H 4 Br 6 484.7 at 760mmHg Alpha hexachlorocyclohexane 319-84-6C 6 H 6 Cl 6 561 Beta hexachlorocyclohexane 319-85-7C 6 H 6 Cl 6 333 at 0.5 mmHg Lindane58-89-9C 6 H 6 Cl 6 323.4 at 760 mmHg Tetrabromodiphenyl ether5436-43-1 C 12 H 6 Br 4 O395.5 at 760mmHg Pentabromodiphenyl ether60348-60-9C 12 H 5 Br 5 O> 200 Hexabromodiphenyl ether68631-49-2C 12 H 4 Br 6 O467 Heptabromodiphenyl ether446255-22-7C 12 H 3 Br 7 O498 Perfluorooctane sulfonic acid (PFOS) 1763-23-1C 8 F 17 O 3 S260 Perfluorooctane sulfonyl fluoride (PFOS-F) 307-35-7C 8 F 18 O 2 S154.1 at 760 mmHg Pentachlorobenzene (PeCB)608-93-5C 6 HCl 5 275-277

8. Method of stacking sample for News POPs USEPA Method 10 or CETESB L9.232 03 sample by source There is no established periodicity Minimum sampling volume of 2.7 Nm3 Sample equipment shall be of PTFE/ Glass

9. Equipment sampling

10. Calibration sampling equipment Wet gasometer Dry gasometer Pitot Method CETESB E16.030 - Duct and Stack Stationary Source - Calibration of Sampling Equipment Used in Air Emission - Test Method (July/09).

11. Thank you!! Gracias !! Obrigada !! mcpoli@sp.gov.br