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Physical Property Describes form or behavior of matter
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Independent of sample size (density, melting point, boiling point, etc.) Intensive Properties
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Depend on how much stuff! (Mass & Volume) Extensive Properties
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Chemical Property Describes how matter interacts with other matter
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Chemical Change Identity Change A new substance is formed.
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Chemical Change Identities change! Note: particle diagram shows conservation of mass: same # of each type of atom on reactant and product sides.
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Monatomic One-atom Molecule
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2 or more uppercase letters in formula Compound
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Physical Change Identity stays the same
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H 2 O(l) H 2 O(g) Phase changes are physical changes. Identity stays the same.
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2H 2 O(l) 2H 2 + O 2 (g) Identity changes. Chemical change.
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Diatomic 2-Atom Molecule
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Smallest particle of an element that retains the properties of the element and that can participate in a chemical reaction. Atom
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Gases Take the shape & volume of their container
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Physical Constant Physical property expressed with a # & unit. Independent of sample size.
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Liquids Definite volume but no definite shape
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Solids Definite volume & definite shape
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Compound 2 or more elements chemically combined
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Element Cannot be broken down into anything simpler by ordinary chemical or physical methods
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Mixture Physical combination of 2 or more pure substances.
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Pure Substances Elements & Compounds
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Pure Substances Type of Matter? The particles in each case are identical to each other.
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Mixtures Heterogeneous or Homogeneous
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Heterogeneous Mixtures Type of Mixtures?
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Homogeneous Mixtures! Type of Mixtures?
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Pure Substance! Mixture or Pure Substance?
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Distillation Physical method of separating mixture of 2 or more liquids based on differences in boiling points.
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Solution Homogeneous Mixture. Liquid & gas phase solutions transmit light. Look translucent. Do not separate on standing.
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Suspension Heterogeneous Mixture. Scatter light. Look cloudy. Need to be shaken or stirred. Separate on standing.
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NaCl(aq) Homogeneous Mixture. NaCl dissolved in water.
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NaCl(s) Pure substance. NaCl in the solid phase.
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Variable Composition Mixture
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NaCl(l) Pure substance. NaCl in the liquid phase.
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NaCl(g) Pure substance. NaCl in the gas phase.
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Homogeneous Uniform, constant, the same throughout.
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Always Homogeneous Pure substance: Element or Compound
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Filtration Physical separation technique used to separate heterogeneous mixtures. Based on differences in particle size.
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Sorting Physical separation technique used to separate heterogeneous mixtures. Based on differences in appearance.
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Definite & Unique Properties Pure substance. Element or Compound.
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Broken into components by chemical decomposition reaction Compound
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Definite Composition Pure substance. Element or Compound.
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Separated by physical technique Mixture
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Triatomic 3-atom Molecule
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May be homogeneous or heterogeneous Mixture
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Compare pure substances & mixtures Pure SubstancesMixtures Unique PropertiesNo unique properties Definite CompositionVariable Composition Always Homogeneous in a single phase May be homogeneous or heterogeneous Elements cannot be broken down. Compounds can be separated into elements using chemical separation techniques. Can be separated into component substances using physical methods.
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Density, melting point, boiling point Examples of physical constants
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Law of conservation of mass (lab scale) Total Mass of Reactants = Total Mass of Products
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Law of conservation of mass (microscale) Total # of atoms of each type on reactant side =Total # of atoms of each type on reactant side = Total # of atoms of each type on product sideTotal # of atoms of each type on product side
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No new properties. Properties are a mix of properties of components. Mixture
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C 6 H 12 O 6 (s) C 6 H 12 O 6 (aq) Equation represents dissolving. Dissolving is a physical change.
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Physical Properties Used to identify substances.
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Atoms can vibrate back & forth about a fixed position. Solid state
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Ways to separate heterogeneous mixtures Sorting Filtration Crystallization Evaporation Distillation Chromatography Differences in density Differences in magnetic properties Differences in solubility
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Change of phase terms Evaporation = l to g Freezing = l to s Melting = s to l Condensation = g to l Boiling = l to g Deposition = g to s Fusion = s to l Sublimation = s to g
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Names of Phase Changes Melting or Fusion Evaporation, Boiling, or Vaporization
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Molecules are relatively far apart from each other & can move from place to place. Gas Phase
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Molecules are pretty close, but have enough room to slide past each other. Liquid Phase
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One substance dissolved in another substance Solution
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Homogeneous mixture in a single phase Solution
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CANNOT be separated by filtration. Liquid phase MUST be evaporated. Solution
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(aq) means dissolved in water It’s a solution! NaCl(aq)
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Heterogeneous mixture of a solid in a liquid Must be shaken or stirred constantly Looks murky or opaque Suspension
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Solid phase can be separated by filtration Suspension
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Heterogeneous Mixture SiO 2 (s) + NaCl(aq) Separate the sand by filtration. Evaporate the water to retrieve the salt.
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Phase at room temperatrue Physical property
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Chromatography Physical separation technique based on differences in intermolecular forces.
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Vapor Gas phase of a substance that is usually a liquid at room temperature.
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Names for some chemical changes Corrosion, Decomposition, Neutralization, Burning, Fermentation, Rotting
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# of atoms of each element before = # of atoms of each element after Law of Conservation of Mass
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Percent Part X 100% Whole
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1 upper case letter in formula Element
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Cutting, Crumpling, Tearing, Pulling into wire, Hammering into sheet Examples of physical changes
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Phase Changes Examples of physical changes
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Evidence of Chemical Change Production of heat & lightProduction of heat & light Formation of a gas (bubbles)Formation of a gas (bubbles) Formation of a precipitateFormation of a precipitate Change in identifying propertiesChange in identifying properties
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Opposite of dissolving. Solid comes out of solution. Precipitation
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Particles arranged in a regular geometric pattern. Solid
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Potential Energy S L G Endothermic Exothermic
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The solid phase: the particles are closest together! (Molecules are always attracted to one another.) For a given substance, which phase has the lowest potential energy?
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They are the same size! How do the centigrade degree and the Kelvin compare?
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Phase change: sublimation Endothermic H 2 O(s) H 2 O(g)
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Phase Change: condensation Exothermic H 2 O(g) H 2 O(l)
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Phase change: melting endothermic H 2 O(s) H 2 O(l)
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CO 2 (s) or dry ice and I 2 (s) Two common substances that sublimate?
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Mixture Pure Substance
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Molecules have potential energy as a result of their structure and composition. Chemical Potential Energy
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