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Chapter 131 Properties of Solutions Chapter 13
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2 Homework 13.10, 13.18, 13.26, 13.32, 13.44, 13.46, 13.48, 13.56
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Chapter 133 The Solution Process Solution - A homogeneous mixture composed of a solute and a solvent. Solute – The substance which is dissolved. Solvent – The substance which acts as the dissolving medium.
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Chapter 134 Saturated Solutions and Solubility Qualitative Terms: Dilute Solution – A solution in which additional solute may be dissolved. Saturated Solution – A solution in which no more solute may be dissolved. Supersaturated Solution – A solution in which more solute is dissolved than in a saturated solution. Solubility - amount of solute required to form a saturated solution. Mole Fraction, Molarity, and Molality
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Chapter 135 Ways of Expressing Concentration
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Chapter 136 Ways of Expressing Concentration
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Chapter 137 Ways of Expressing Concentration Mole Fraction
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Chapter 138 Ways of Expressing Concentration Molarity
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Chapter 139 Ways of Expressing Concentration Molality (m) – moles of solute per kilogram of solvent Molality
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Chapter 1310 Ways of Expressing Concentration Molality (m) – moles of solute per kilogram of solvent Molality
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Chapter 1311 Factors Affecting Solubility Miscible liquids - Mix in any proportions. Immiscible liquids - Do not mix. Solute-Solvent Interactions
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Chapter 1312 Factors Affecting Solubility “Like Dissolves Like” -Polar molecules will dissolve in polar solvents. -Non-polar molecules will dissolve in non-polar solvents. Solute-Solvent Interactions
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Chapter 1313 Factors Affecting Solubility -Solubility of a gas in a liquid is a function of the pressure of the gas. -The higher the pressure, the greater the solubility. Pressure Effects
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Chapter 1314 Factors Affecting Solubility Henry’s Law – The solubility of a gas increases in direct proportion to its partial pressure above the solution. Pressure Effects
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Chapter 1315 Factors Affecting Solubility Henry’s Law – The solubility of a gas increases in direct proportion to its partial pressure above the solution. C g - solubility of gas P g - the partial pressure of the gas k - Henry’s law constant. Pressure Effects
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Chapter 1316 Factors Affecting Solubility Temperature Effects
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Chapter 1317 Factors Affecting Solubility Temperature Effects
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Chapter 1318 Colligative Properties -Properties of a solution which depend on quantity of solute molecules. -Solutions formed with a nonvolatile solute will: -have lower vapor pressure -lower freezing point -higher boiling point
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Chapter 1319 Colligative Properties Boiling-Point Elevation
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Chapter 1320 Colligative Properties Raoult’s Law – The equilibrium vapor pressure of the solvent over the solution is directly proportional to the mole fraction of the solvent in the solution Raoult’s Law
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Chapter 1321 Colligative Properties Raoult’s Law – The equilibrium vapor pressure of the solvent over the solution is directly proportional to the mole fraction of the solvent in the solution P A - vapor pressure of the solvent in the solution P A - vapor pressure of the pure solvent A - the mole fraction of solvent, A Raoult’s Law
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Chapter 1322 Colligative Properties K b - Molal boiling-point elevation constant m – solution molality T b – boiling point change Boiling-Point Elevation
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Chapter 1323 Colligative Properties K f - Molal freezing-point depression constant m – solution molality T f – freezing point change Freezing-Point Depression
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Chapter 1324 Colligative Properties The net movement of solvent through a semi-permeable membrane from a dilute to a concentrated solution. Osmosis
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Chapter 1325 Colligative Properties Eventually the pressure difference between the arms stops osmosis. Osmosis
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Chapter 1326 Colligative Properties Osmotic pressure( ) - The pressure required to stop osmosis Osmosis
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Chapter 1327 Colligative Properties Osmotic pressure( ) - The pressure required to stop osmosis M - molarity of the solution R - gas constant (0.08206 L(atm)/mol(K)) T - temperature in Kelvin Osmosis
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Chapter 1328 Colloids -Colloids are suspensions in which the suspended particles are larger than molecules but too small to drop out of the suspension due to gravity. -Particle size: 10 to 2000 Å.
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Chapter 1329 Colloids Tyndall effect: ability of a Colloid to scatter light. The beam of light can be seen through the colloid.
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