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Aluminum-induced in situ crystallization of HWCVD a-Si:H films

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Presentation on theme: "Aluminum-induced in situ crystallization of HWCVD a-Si:H films"— Presentation transcript:

1 Aluminum-induced in situ crystallization of HWCVD a-Si:H films
指導教授:管 鴻 教授 學 生:郭豐榮

2 Outline INTRODUCTION EXPERIMENTAL RESULTS AND DISCUSSION CONCLUSION
REFERENCES

3 INTRODUCTION Thin-film polycrystalline silicon is nowadays drawing a lot of interest due to its potential use in electronic devices. we show for the first time the AIC of HWCVD a-Si:H films without the subsequent annealing step.Thus, one can avoid the post-deposition annealing step by depositing Al at an appropriate temperature.

4 EXPERIMENTAL glass a-Si:H Al Al a-Si:H annealing Raman XRD
By HWCVD at a substrate temperature of 300 °C, with silane flow of 10 sccm and pressure of 70 mTorr. Distance between filament and substrate was 5 cm and filament temperature used was 1700 °C and deposition rate was 1 nm/s. (a) (b) a-Si:H Al Al a-Si:H annealing Raman XRD

5 RESULTS AND DISCUSSION
Raman spectra for samples with different Al thicknesses of (a) 10 nm, (b) 40 nm, and (c) 60 nm and constant a-Si:H (600 nm) thickness after annealing at 400 °C for 4 h

6 RESULTS AND DISCUSSION
XRD plot of the sample with Al (60 nm) deposited on a-Si:H (600 nm) after annealing at 400 °C for 4 h

7 RESULTS AND DISCUSSION
Raman spectra for (a) glass/a-Si:H (350 nm) and (b) glass/a-Si:H (450 nm) on which Al (50 nm) is deposited at 300 °C.

8 RESULTS AND DISCUSSION
XRD plot for glass/a-Si:H (450 nm) on which Al (50 nm) is deposited at 300 °C

9 CONCLUSION Through AIC of HWCVD a-Si:H films, it is possible to achieve higher grain sizes in the poly-Si film suitable for electronic devices. By depositing the Al at moderate temperature of about 300 °C, it is possible to avoid ex situ annealing step and also reduce the processing temperature for AIC.

10 REFERENCES [1] R.B. Bergmann, G. Oswald, M. Albrecht, V. Gross, Sol. Energy Mater.Sol. Cells 147 (1997) 46. [2] T. Matsuyama, N. Terada, T. Baba, T. Sawada, S. Tsuge, K. Wakisaka, S.Tsuda, J. Non-Cryst. Solids 198 (1996) 940. [3] T.J. Konno, R. Sinclair, Mater. Sci. Eng. A179/A180 (1994) 426. [4] S. Gall, M. Muske, I. Sieber, O. Nast, W. Fuhs, J. Non-Cryst. Solids 299– (2002) 741. [5] O. Nast, S.R. Wehnman, J. Appl. Phys. 88 (1) (2000) 124. [6] D. Malinovsko, G. Grigorov, M. Dimitrova, A. Angelov, N. Peev, Thin Solid Films 501 (2005) 358. [7] G.J. Qi, S. Zhang, T.T. Tang, J.F. Li, X.W. Sun, X.T. Zeng, Surf. Coat.Technol. 198 (2005) 300. [8] O. Nast, A.J. Hartmann, J. Appl. Phys. 88 (2) (2000) 716.


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