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Chapter 2 - Section 3 Suggested Reading Pages 44 - 57 Using Scientific Measurements
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Accuracy vs. Precision Accuracy - how close a measurement is to the accepted value Precision - how close a series of measurements are to each other ACCURATE = CORRECT PRECISE = CONSISTENT
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Neither
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Precision
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Accuracy & Precision
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Percent Error Indicates accuracy of a measurement experimental value – accepted value accepted value X 100 % Error =
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Making Measurements Write down all certain or exact digits you can read off the instrument, AND one more estimated digit. Measuring always involves some estimation.
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*Uncertainty Estimate the last digit Uncertainty is plus-or-minus based on the estimated digits place. The ratio of the estimated uncertainty to the smallest scale division depends on the separation between the markings.
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Left: 1.5 ± 0.5 inches Right: 1.48 ± 0.01 inches
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30.0 ± 0.1 degrees C
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Read at the bottom of the meniscus 4.86 ± 0.01 ml
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Try to read these and estimate uncertainty correctly.
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Left: 5.75 ± 0.01 mL
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Middle: 3.0 ± 0.5 mL
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Right: 0.35 ± 0.05 mL
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*Mercury Meniscus is inverted
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Significant Figures Indicate precision of a measurement. Recording Significant Figures Significant figures in a measurement include the known digits plus a final estimated digit 2.32 cm
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Counting Significant Figures Count all numbers EXCEPT: Leading zeros -- 0.0025 Trailing zeros without a decimal point -- 2,500
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4. 0.080 3. 5,280 2. 402 1. 23.50 Significant Figures Significant Figures Examples: 1. 23.50 2. 402 3. 5,280 4. 0.080 4 sig figs 3 sig figs 2 sig figs
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Multiply/Divide - The # with the fewest sig figs determines the # of sig figs in the answer. (13.91g/cm 3 )(23.3cm 3 ) = 324.103g 324 g 4 SF3 SF Sig Fig Rules
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Add/Subtract - The # with the fewest digits to the right of the decimal place determines the place of the last sig fig in the answer. 3.75 mL + 4.1 mL 7.85 mL 7.9 mL 3.75 mL + 4.1 mL 7.85 mL
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Significant Figures Add/Subtract – working with whole numbers, round so the final sig fig is in the same place as the leftmost uncertain digit. 224 g + 130 g 354 g 350 g 224 g + 130 g 354 g
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Significant Digits Exact Numbers do not limit the # of sig figs in the answer. Counting numbers: 12 students Exact conversions: 1 m = 100 cm “1” in any conversion: 1 in = 2.54 cm
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Significant Digits 5. (15.30 g) ÷ (6.4 mL) Practice Problems = 2.390625 g/mL 18.1 g 6. 18.9g - 0.84 g 18.06 g 4 SD2 SD 2.4 g/mL 2 SD
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Scientific Notation Converting into Sci. Notation: Move decimal until there’s 1 digit to its left. Places moved = exponent. Large # (>1) positive exponent Small # (<1) negative exponent Only include significant digits. 65,000 kg 6.5 × 10 4 kg
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Practice Problems 7. 2,400,000 g 8. 0.00256 kg 9.7 10 -5 km 10.6.2 10 4 mm 2.4 10 6 g 2.56 10 -3 kg 0.00007 km 62,000 mm = = = =
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Calculating with Sci. Notation (5.44 × 10 7 g) ÷ (8.1 × 10 4 mol) = 5.44 EXP EE ÷ ÷ EXP EE ENTER EXE 78.1 4 = 671.6049383= 670 g/mol= 6.7 × 10 2 g/mol Type on your calculator:
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Proportions Direct Proportion Inverse Proportion y x y x
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Percent A fraction can be written as a percent by converting it to a decimal and then multiplying by 100. Ex: 900 million kilograms of plastic soda bottles are produced each year. 180 million kilograms of them are recycled. 900 million kg = 0.2 x 100% = 20% 180 million kg
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