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Published byTracy Harvey Modified over 9 years ago
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e- Transfer Theory Electrons move from the anode to the cathode (from the SRA to the SOA)
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Electrical Current (I) The movement of electrons produces and electric current (I) which is measured in Amperes = 1 coulomb/sec.
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Charge (Q) Charge is the product of current and time (measured in coulombs) Q = It
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Q = charge in Coulombs I = current in Amperes (coulombs/second) t = time in Seconds
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Faraday’s constant The value of the electric charge carried by one mole of electrons (or the molar charge of electrons) F = 9.65x10 4 C/mol e-
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The number of moles of e- can be found using electric charge and Faraday’s constant n e- = Q F
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Q = It n e- = It F
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By finding the moles of electrons, we can find the mass of the product produced in a cell!!!
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Example To find the mass of copper produced by an electrolytic cell in 1 hour at 4.0A Cu2+(aq) + 2e- Cu(s)
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Example 2: In the electrolysis of silver, the electrolytic cell is operating at 5.00A. How long must it run to produce 4.0g of Ag(s) at the cathode? Ag+(aq) + 1e- Ag(s)
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