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Chemical Reactions of Alkanes 1. Combustion 2. Desaturation- forms alkenes 3. Halogenation- forms alkyl halides
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Chemical Reactions of Alkanes: Combustion
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Chemical Reactions of Alkanes: Desaturation- forms alkenes
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Chemical Reactions of Alkanes: Halogenation- forms alkyl halides
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Mechanism of Halogenation is Free Radical Based
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2 nd Step in Mechanism of Halogenation is Elongation
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Various Combinations of Free Radicals Represent Termination
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Nomenclature of Alkyl Halides 1. Chain as alkanes 2. -ine of halogen changed to -o 3.Identify attachment site e.g. 2-chloroethane
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Physical Properties of Alkyl Halides 1. Polar 2. Liquid instead of gas 3. Tend to be toxic, taken internally
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Predominant Product Determined by radical stability Direction of stability
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Stereochemistry Chiral Carbon- a carbon which has four different groups bonded to it Dashed wedge: behind; solid wedge, in front Enantiomers- nonsuperimposable, mirror images
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The RS system of nomenclature 1. Position the molecule so the H is in back 2. Number highest mol. wt. (1) to lowest (3) 3. Clockwise R, counterclockwise S
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Alkenes: Names and Structures Alkenes- hydrocarbons that have one or more double bonds between carbon atoms C n H 2n Monounsaturated- one double bond Polyunsaturated- two or more double bonds
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Naming Alkenes 1. Find the longest continuous carbon chain that contains the double bond(s), even if it is not the longest carbon chain, and number from the end nearer the double bond. 2. Write the alkane name corresponding to the longest carbon chain, then change the -ane suffix to -ene. 3. Identify by number the lower-numbered carbon atom containing a double bond, followed by a hyphen directly before the alkene name; precede this by naming substituents in the usual way. 4. If two or more double bonds occur, specify each double bond by number and use an appropriate prefix before -ene to indicate the number of double bonds.
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Cis-Trans Isomerism 1. “R groups” must be attached to different carbons 2. Larger “R groups” get priority
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Practice Give the IUPAC name for the above molecules
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More Practice Draw the structure of the following compounds, for which a correct IUPAC name is given: cis-3-hexene 3-ethylcyclohexene
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Properties of Alkenes and Alkynes 1. nonpolar 2. less dense than alkanes 3. trend toward gas rather than liquid 4. used to make polymers
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Reactions of Alkenes Addition reaction- since H has been taken away to create a double bond, H or other molecules can be added across the double bond, yielding a substituted alkane. 1. catalytic hydrogenation 2. halogenation 3. addition of HCl and HBr (Markovnikonv's rule) 4. hydration 5. oxidation
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Reactions of Alkenes: Catalytic Hydrogenation
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Reactions of Alkenes: Halogenation
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Reactions of Alkenes: Acid-Catalyzed Hydration (Markovnikov’s Rule)
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Reactions of Alkenes: Addition of HCl and HBr (Markovnikov’s Rule)
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Reactions of Alkenes: Catalytic Hydrogenation Addition reaction- since H has been taken away to create a double bond, H or other molecules can be added across the double bond, yielding a substituted alkane. 1. catalytic hydrogenation 2. halogenation 3. addition of HCl and HBr (Markovnikonv's rule) 4. hydration 5. Others exist
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Alkynes: Names and Structures Alkynes- hydrocarbons that have one or more triple bonds between carbon atoms C n H 2n-2 Named as alkenes, with the exception that -yne is used instead of -ene
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Reactions of Alkynes Since H has been taken away to create the triple bond, just as for a double bond, the same reactions will occur for alkynes as alkenes. The difference is, 2 moles will be added instead of 1.
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