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13.19 Infrared Spectroscopy Gives information about the functional groups in a molecule
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C C C C C HCCH H2CH2CH2CH2C CH 2 C CO
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texttext text
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texttext text C C
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region of infrared that is most useful lies between 2.5-16 m (4000-625 cm -1 ) depends on transitions between vibrational energy states stretchingbending Infrared Spectroscopy
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Stretching Vibrations of a CH 2 Group SymmetricAntisymmetric
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Bending Vibrations of a CH 2 Group In plane
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Bending Vibrations of a CH 2 Group Out of plane
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Fig. 13.26 (page 520)
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Example of infrared spectrum Hexane Transmittance (%) 100 0 Wave number, cm -1 440036002800200016001200800 C—H stretching bending bending bending
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Example of infrared spectrum Hexane Transmittance (%) 100 0 Wave number, cm -1 440036002800200016001200800 no peaks higher than 3000 cm -1
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Infrared spectrum of 1-hexene Transmittance (%) 100 0 Wave number, cm -1 440036002800200016001200800 peak higher than 3000 cm -1 C=C—H C=C CH 2 =C—
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Structural unitFrequency, cm -1 Stretching vibrations (single bonds) sp C—H3310-3320 sp 2 C—H3000-3100 sp 3 C—H2850-2950 sp 2 C—O1200 sp 3 C—O1025-1200 Table 13.4 (p 519) Infrared Absorption Frequencies
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Structural unitFrequency, cm -1 Stretching vibrations (multiple bonds) Table 13.4 (p 519) Infrared Absorption Frequencies C C 1620-1680—CN —CC— 2100-2200 2240-2280
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Structural unitFrequency, cm -1 Stretching vibrations (carbonyl groups) Aldehydes and ketones1710-1750 Carboxylic acids1700-1725 Acid anhydrides1800-1850 and 1740-1790 Esters1730-1750 Amides1680-1700 Table 13.4 (p 519) Infrared Absorption Frequencies C O
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Structural unitFrequency, cm -1 Bending vibrations of alkenes Table 13.4 (p 519) Infrared Absorption Frequencies CH 2 RCH R2CR2CR2CR2C CHR' cis-RCH CHR' trans-RCH CHR' R2CR2CR2CR2C910-990 890 665-730 960-980 790-840
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Structural unitFrequency, cm -1 Bending vibrations of derivatives of benzene Monosubstituted730-770 and 690-710 Ortho-disubstituted735-770 Meta-disubstituted750-810 and 680-730 Para-disubstituted790-840 Table 13.4 (p 519) Infrared Absorption Frequencies
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Infrared spectrum of 1-hexene Transmittance (%) 100 0 Wave number, cm -1 440036002800200016001200800 C=C stretch CH 2 =C— bend
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Infrared spectrum of tert-butylbenzene Transmittance (%) 100 0 Wave number, cm -1 440036002800200016001200800 Ar—H stretch; > 3000 monosubstituted benzene
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Structural unitFrequency, cm -1 Stretching vibrations (single bonds) O—H (alcohols)3200-3600 O—H (carboxylic acids) 3000-3100 N—H3350-3500 Table 13.4 (p 519) Infrared Absorption Frequencies
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Infrared spectrum of 2-hexanol Transmittance (%) 100 0 Wave number, cm -1 440036002800200016001200800 O—H stretch C—H stretch
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Infrared spectrum of 2-hexanone Transmittance (%) 100 0 Wave number, cm -1 440036002800200016001200800 C=O stretch C—H stretch
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