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Table 15-1, p. 612. Common Names of Carboxylic Acids Table 15.1.

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Presentation on theme: "Table 15-1, p. 612. Common Names of Carboxylic Acids Table 15.1."— Presentation transcript:

1 Table 15-1, p. 612

2 Common Names of Carboxylic Acids Table 15.1

3 Common Names of Dicarboxylic Acids Table 15.1

4 p. 614

5 p. 615

6 Fig. 15-1, p. 616

7 p. 616

8 Table 15-2, p. 615

9 p. 618

10

11

12 Fig. 9-16, p. 338 Electrophilic Aromatic Substitution

13 Fig. 9-16, p. 338 pKa’s of Substituted Benzoic Acids Lower pKa Higher pKa

14 p. 620 Preparation of Carboxylic Acids : Review 1.Oxidation of 1  alcohols: a. b.

15 p. 620 Preparation of Carboxylic Acids : Review 1.Oxidation of 1  alcohols: a. CrO 3, H 2 SO 4 b. K 2 Cr 2 O 7, H 3 O + 1.Oxidation of 1  alcohols:

16 p. 620 Preparation of Carboxylic Acids : Review 2. Oxidation of aldehydes: a. b. 1.Oxidation of 1  alcohols:

17 p. 620 Preparation of Carboxylic Acids : Review 2. Oxidation of aldehydes: a. CrO 3, H 2 SO 4 b. K 2 Cr 2 O 7, H 3 O + 1.Oxidation of 1  alcohols:

18 p. 620 Preparation of Carboxylic Acids : Review 3. Oxidative cleavage a. of aryl benzenes (sect 9.10): b. carbon-carbon double bonds : i. ii. Methyl, 1°, 2°

19 p. 620 Preparation of Carboxylic Acids : Review 3. Oxidative cleavage a. of aryl benzenes (sect 9.10): KMnO 4 b. carbon-carbon double bonds : i. ii. Methyl, 1°, 2°

20 p. 620 Preparation of Carboxylic Acids : Review 3. Oxidative cleavage a. of aryl benzenes (sect 9.10): KMnO 4 b. carbon-carbon double bonds : i. (sect 8.8) KMnO 4 ii. Methyl, 1°, 2°

21 p. 620 Preparation of Carboxylic Acids : Review 3. Oxidative cleavage a. of aryl benzenes (sect 9.10): KMnO 4 b. carbon-carbon double bonds : i. (sect 8.8) KMnO 4 ii. O 3, H 2 O 2 Methyl, 1°, 2°

22 p. 620 Preparation of Carboxylic Acids : Review 3. Oxidative cleavage a. of aryl benzenes (sect 9.10): KMnO 4 b. carbon-carbon double bonds : i. (sect 8.8) KMnO 4 ii. O 3, H 2 O 2 Methyl, 1°, 2°

23 p. 620 Preparation of Carboxylic Acids : 1.Oxidative Cleavage: a. O 3, H 2 O 2 2. Reduction of Carbon Dioxide: a. Examples b. Mechanism c. Limitations

24 p. 620 Preparation of Carboxylic Acids : 3. Hydrolysis of Nitriles a. Examples b. Limitations c. Mechanisms i.Acid catalyzed ii.Base catalyzed

25 p. 620 Preparation of Nitriles 1.From Alkyl Halides 2. From Amides

26 p. 620 Reactions of Nitriles with Reducing Agents 1.Lithium Aluminum Hydride 2. Grignard Reagents

27 Fig. 15-4, p. 627

28 p. 628

29 Fig. 15-5, p. 628

30 End


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