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Chapter 11 Chemical Reactions 11.2 Types of Chemical Reactions

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1 Chapter 11 Chemical Reactions 11.2 Types of Chemical Reactions
11.1 Describing Chemical Reactions 11.2 Types of Chemical Reactions 11.3 Reactions in Aqueous Solution Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved.

2 Classifying Reactions
Do Now: Balance these chemical reactions. ___ C2H4O4 + ___ O2 → ___ CO2 + ___ H2O ___ Ni + ___ H2SO4 → ___ H2 + ___ Ni2(SO4)3 Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved.

3 Classifying Reactions
Do Now: Balance these chemical reactions. 1 C2H4O4 + 1 O2 → 2 CO2 + 2 H2O Ni + 3 H2SO4 → 3 H2 + 1 Ni2(SO4)3 Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved.

4 5 Types of Chemical Reactions Combination Decomposition
Classifying Reactions 5 Types of Chemical Reactions Combination Decomposition Single-replacement Double-replacement Combustion. Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved.

5 A + B AB 2 Mg + O2 2 MgO Combination Reactions
Classifying Reactions Combination Reactions Two or more substances react to form a single new substance. A + B AB 2 Mg + O MgO Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved.

6 A + B AB Combination Reactions
Classifying Reactions Combination Reactions Two or more substances react to form a single new substance. A + B AB + Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved.

7 Combination Reactions
Classifying Reactions Combination Reactions When a Group A metal and a nonmetal react, the product is a binary ionic compound. 2K(s) + Cl2(g) → 2KCl(s) Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved.

8 Combination Reactions
Classifying Reactions Combination Reactions When two nonmetals react in a combination reaction, more than one product is often possible. S(s) + O2(g) → SO2(g) sulfur dioxide 2S(s) + 3O2(g) → 2SO3(s) sulfur trioxide Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved.

9 Combination Reactions
Classifying Reactions Combination Reactions More than one product may also result from a transition metal and nonmetal. Fe(s) + S(s) → FeS(s) iron(II) sulfide 2Fe(s) + 3S(g) → Fe2S3(s) iron(III) sulfide Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved.

10 AB A + B 2 BaO 2Ba + O2 Decomposition Reactions
Classifying Reactions Decomposition Reactions A single compound breaks down into two or more products. AB A + B 2 BaO Ba + O2 Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved.

11 AB A + B + Decomposition Reactions
Classifying Reactions Decomposition Reactions A single compound breaks down into two or more products. AB A + B + Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved.

12 AB A + B 2H2O2 2H2O + O2 Decomposition Reactions
Classifying Reactions Decomposition Reactions A single compound breaks down into two or more products. AB A + B 2H2O H2O + O2 Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved.

13 AB + C AC + B AB + C C B + A Single Replacement Reactions
Classifying Reactions Single Replacement Reactions One element replaces a second element in a compound (based on activity series). AB + C AC + B AB + C C B + A Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved.

14 AB + C AC + B AB + C C B + A + + Single Replacement Reactions
Classifying Reactions Single Replacement Reactions One element replaces a second element in a compound (based on activity series). AB + C AC + B AB + C C B + A Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved.

15 AB + C AC + B AB + C C B + A MgCl2 + 2Na Mg + 2NaCl
Classifying Reactions Single Replacement Reactions One element replaces a second element in a compound (based on activity series). AB + C AC + B AB + C C B + A MgCl2 + 2Na Mg + 2NaCl 2HCl + F HF + Cl2 Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved.

16 Activity Series of Metals
Classifying Reactions Single-Replacement Reactions Whether one metal will displace another metal from a compound depends upon the relative reactivities of the two metals. Activity Series of Metals Name Symbol Lithium Li Calcium Ca Sodium Na Magnesium Mg Aluminum Al Zinc Zn Iron Fe Lead Pb Copper Cu Mercury Hg Silver Ag Decreasing reactivity The activity series of metals lists metals in order of decreasing reactivity. A reactive metal will replace any metal listed below it in the activity series. Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved. 16

17 Single-Replacement Reactions
Classifying Reactions Single-Replacement Reactions A halogen can also replace another halogen from a compound. The activity of halogens decreases as you go down Group 7A of the periodic table—fluorine, chlorine, bromine, and iodine. Bromine is more active than iodine, so this reaction occurs: Br2(aq) + 2NaI(aq) → 2NaBr(aq) + I2(aq) But bromine is less active than chlorine, so this reaction does not occur: Br2(aq) + NaCl(aq) → No reaction Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved.

18 AB + CD AD + CB + + Double-Replacement Reactions
Classifying Reactions Double-Replacement Reactions Reactant cations exchange places to form new compounds. AB + CD AD + CB Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved.

19 AB + CD AD + CB Double-Replacement Reactions
Classifying Reactions Double-Replacement Reactions Reactant cations exchange places to form new compounds. AB + CD AD + CB MgSO4 + K2CO K2SO4 + MgCO3 MgCl2 + 2HNO Mg(NO3)2 + 2HCl Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved.

20 Classifying Reactions
Combustion Reactions A hydrocarbon reacts with oxygen to produce carbon dioxide, water, and energy (in the form of heat and light). CxHy + O CO2 + H2O 2C8H O2 → 16CO2 + 18H2O Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved.

21 Classifying Reactions
Now that you have learned about some of the basic reaction types, you can predict the products of many reactions. The number of elements and/or compounds reacting is a good indicator of possible reaction type and, thus, possible products. Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved.

22 END OF 11.2 Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved.


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