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Maharaja Sayajirao Vidyalaya,Satara.
Rayat shikshan Sanstha’s Maharaja Sayajirao Vidyalaya,Satara. Science and Technology Part-I PowerPoint Presentation by Shri- Sadawarte M.D. Unit - Electrolysis
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Electrolysis of copper chloride
Electrolysis-Decomposition of an electrolyte by passage of an electric current through it is called ‘electrolysis’.. Electrolysis of copper chloride( CuCl2) Construction of electrolytic cell- Electrodes – carbon rods Electrolyte – copper chloride solution(2 g in 150 ml water ) Connect battery, bulb or ammeter and switch in circuit.
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Electrolysis of copper chloride
Procedure – Switch on the current in the circuit for 5 to 15 min and observe the changes at electrodes & colour of solution. Observations – i)Cathode-portion dipped in solution become reddish. ii) Anode- bubbles of gas are observed at anode. iii)The colour of copper chloride solution appears to fade out.
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Classification of elements
Conclusion- i)The reddish substance at cathode is copper. ii)The gas observed at anode is chlorine. iii) The colour fading of copper chloride solution shows that concentration of solution decreases
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Electrolysis of copper chloride
Reactions And expiation There are Cu2+ ions and Cl- ions in aqueous solution of copper chloride (CuCl2) When electric current is passed through the circuit i) Cu2+ ions are attracted towards cathode. There they accept the electrons and copper is deposited at cathode. Cu2+ +2e- →Cu (cathode reaction) ii)Cl- ions are attracted towards the anode .There they loose electrons and chlorine gas is evolved at anode. 2Cl- →Cl2 + 2e- ( Anode reaction ) iii) Thus in electrolysis of CuCl2 , Copper is deposited at cathode & chlorine gas is evolved at anode. Cu2+ + 2Cl- →Cu + Cl2 ( cell reaction)
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Question:- Describe the electrolysis of copper chloride.
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