1. C-H Insertion Story Justin Du Bois associate professor : University of Stanford B.S. : University of California at Berkeley (1992) Ph.D. : California Institute of Technology (1997) (Erick M. Carreira) NIH Postdoctoral fellow : Massachusetts Institute of Technology (1997-1999) (Stephen J. Lippard)

2. A Rh-Catalyzed C-H Insertion Reaction for the Oxidative Conversion of Carbamates to Oxazolidinones Espino, C. G.; Du Bois, J. Angew. Chem., Int. Ed.. 2001, 40, 598-600.

3. A Rh-Catalyzed C-H Insertion Reaction for the Oxidative Conversion of Carbamates to Oxazolidinones (optimization) Espino, C. G.; Du Bois, J. Angew. Chem., Int. Ed.. 2001, 40, 598-600. Base : K 2 CO 3, Na 2 HPO 4, 2,6-di-tert- butyl-4-pyridine, BaO, MgO Oxydant : PhI=O, PhI(O2CCF3)2. PhI(OMe)2, 2-iodosobenzoic acid

4. A Rh-Catalyzed C-H Insertion Reaction for the Oxidative Conversion of Carbamates to Oxazolidinones (scope) Espino, C. G.; Du Bois, J. Angew. Chem., Int. Ed.. 2001, 40, 598-600.

5. A Rh-Catalyzed C-H Insertion Reaction for the Oxidative Conversion of Carbamates to Oxazolidinones (mechanism) Espino, C. G.; Du Bois, J. Angew. Chem., Int. Ed.. 2001, 40, 598-600.

6. Synthesis of 1,3-Difunctionalized Amine Derivatives through Selective C-H Bond Oxidation Espino, C. G.; Wehn, P. M.; Chow, J.; Du Bois, J. J. Am. Chem. Soc. 2001, 123, 6935-6936.

7. Synthesis of 1,3-Difunctionalized Amine Derivatives through Selective C-H Bond Oxidation (scope) Espino, C. G.; Wehn, P. M.; Chow, J.; Du Bois, J. J. Am. Chem. Soc. 2001, 123, 6935-6936.

8. Synthesis of 1,3-Difunctionalized Amine Derivatives through Selective C-H Bond Oxidation (extension) Espino, C. G.; Wehn, P. M.; Chow, J.; Du Bois, J. J. Am. Chem. Soc. 2001, 123, 6935-6936.

9. Stereoselective Organozinc Addition Reactions to 1,2-Dihydropyrans for the Assembly of Complex Pyran Structures Steinhuebel, D. P.; Fleming, J. J.; Du Bois, J. Org. Lett. 2002, 4, 293-295.

10. Enantioselective Synthesis of the Bromopyrrole Alkaloids Manzacidin A and C by Stereospecific C-H Bond Oxidation Wehn, P. M.; Du Bois, J. J. Am. Chem. Soc. 2002, 124, 12950-12951.

11. Enantioselective Synthesis of the Bromopyrrole Alkaloids Manzacidin A and C by Stereospecific C-H Bond Oxidation (retrosynthesis) Wehn, P. M.; Du Bois, J. J. Am. Chem. Soc. 2002, 124, 12950-12951.

12. Enantioselective Synthesis of the Bromopyrrole Alkaloids Manzacidin A and C by Stereospecific C-H Bond Oxidation (hydrogenation) Wehn, P. M.; Du Bois, J. J. Am. Chem. Soc. 2002, 124, 12950-12951.

13. Enantioselective Synthesis of the Bromopyrrole Alkaloids Manzacidin A and C by Stereospecific C-H Bond Oxidation (synthesis) Wehn, P. M.; Du Bois, J. J. Am. Chem. Soc. 2002, 124, 12950-12951.

14. A Unique and Highly Efficient Method for Catalytic Olefin Aziridination Guthikonda, K.; Du Bois, J. J. Am. Chem. Soc. 2002, 124, 13672-13673.

15. Novel Iminium Ion Equivalents Prepared through C-H Oxidation for the Stereocontrolled Synthesis of Functionalized Propargylic Amine Derivatives Fleming, J. J.; Fiori, K. W.; Du Bois, J. J. Am. Chem. Soc. 2003, 125, 2028-2029.

16. Novel Iminium Ion Equivalents Prepared through C-H Oxidation for the Stereocontrolled Synthesis of Functionalized Propargylic Amine Derivatives (iminium ion equivalents synthesis) Fleming, J. J.; Fiori, K. W.; Du Bois, J. J. Am. Chem. Soc. 2003, 125, 2028-2029.

17. Novel Iminium Ion Equivalents Prepared through C-H Oxidation for the Stereocontrolled Synthesis of Functionalized Propargylic Amine Derivatives (alkynylzinc addition) Fleming, J. J.; Fiori, K. W.; Du Bois, J. J. Am. Chem. Soc. 2003, 125, 2028-2029.

18. Novel Iminium Ion Equivalents Prepared through C-H Oxidation for the Stereocontrolled Synthesis of Functionalized Propargylic Amine Derivatives (alkynylzinc addition : scope) Fleming, J. J.; Fiori, K. W.; Du Bois, J. J. Am. Chem. Soc. 2003, 125, 2028-2029.

19. Novel Iminium Ion Equivalents Prepared through C-H Oxidation for the Stereocontrolled Synthesis of Functionalized Propargylic Amine Derivatives (extension) Fleming, J. J.; Fiori, K. W.; Du Bois, J. J. Am. Chem. Soc. 2003, 125, 2028-2029.

20. Stereochemical Models for Rh-Catalyzed Amination Reactions of Chiral Sulfamates (scope) Wehn, P. M.; Lee, J.; Du Bois, J. Org. Lett. 2003, 5, 4823-4826.

21. Stereochemical Models for Rh-Catalyzed Amination Reactions of Chiral Sulfamates (rational) Wehn, P. M.; Lee, J.; Du Bois, J. Org. Lett. 2003, 5, 4823-4826.

22. Stereochemical Models for Rh-Catalyzed Amination Reactions of Chiral Sulfamates (rational) Wehn, P. M.; Lee, J.; Du Bois, J. Org. Lett. 2003, 5, 4823-4826.

23. Stereochemical Models for Rh-Catalyzed Amination Reactions of Chiral Sulfamates (rational) Wehn, P. M.; Lee, J.; Du Bois, J. Org. Lett. 2003, 5, 4823-4826.

24. Stereochemical Models for Rh-Catalyzed Amination Reactions of Chiral Sulfamates (aziridination : scope) Wehn, P. M.; Lee, J.; Du Bois, J. Org. Lett. 2003, 5, 4823-4826.

25. Stereochemical Models for Rh-Catalyzed Amination Reactions of Chiral Sulfamates (aziridination : rational) Wehn, P. M.; Lee, J.; Du Bois, J. Org. Lett. 2003, 5, 4823-4826.

26. Expanding the Scope of C-H Amination through Catalyst Design Espino, C. G.; Fiori, K. W.; Kim, M.; Du Bois, J. J. Am. Chem. Soc. 2004, 126, 15378-15379.

27. Expanding the Scope of C-H Amination through Catalyst Design Espino, C. G.; Fiori, K. W.; Kim, M.; Du Bois, J. J. Am. Chem. Soc. 2004, 126, 15378-15379.

28. Expanding the Scope of C-H Amination through Catalyst Design Espino, C. G.; Fiori, K. W.; Kim, M.; Du Bois, J. J. Am. Chem. Soc. 2004, 126, 15378-15379.

29. Expanding the Scope of C-H Amination through Catalyst Design Espino, C. G.; Fiori, K. W.; Kim, M.; Du Bois, J. J. Am. Chem. Soc. 2004, 126, 15378-15379.

30. Deacylative Oxidation Strategy for the Preparation of  -Functionalized Carbonyls Brodsky, B. H.; J. J.; Du Bois, J. Org. Lett. 2004, 6, 2619-2621.

31. Rh-Catalyzed Amination of Ethereal C-H Bonds: AVersatile Strategy for the Synthesis of Complex Amines Fiori, K. W.; Fleming, J. J.; Du Bois, J. Angew. Chem., Int. Ed.. 2004, 43, 4349-4352.

32. Rh-Catalyzed Amination of Ethereal C-H Bonds: AVersatile Strategy for the Synthesis of Complex Amines Fiori, K. W.; Fleming, J. J.; Du Bois, J. Angew. Chem., Int. Ed.. 2004, 43, 4349-4352.

33. Rh-Catalyzed Amination of Ethereal C-H Bonds: AVersatile Strategy for the Synthesis of Complex Amines Fiori, K. W.; Fleming, J. J.; Du Bois, J. Angew. Chem., Int. Ed.. 2004, 43, 4349-4352.

34. Rh-Catalyzed Amination of Ethereal C-H Bonds: AVersatile Strategy for the Synthesis of Complex Amines Fiori, K. W.; Fleming, J. J.; Du Bois, J. Angew. Chem., Int. Ed.. 2004, 43, 4349-4352.

35. Rh-Catalyzed Amination of Ethereal C-H Bonds: AVersatile Strategy for the Synthesis of Complex Amines Fiori, K. W.; Fleming, J. J.; Du Bois, J. Angew. Chem., Int. Ed.. 2004, 43, 4349-4352.

36. Rh-Catalyzed Amination of Ethereal C-H Bonds: AVersatile Strategy for the Synthesis of Complex Amines Fiori, K. W.; Fleming, J. J.; Du Bois, J. Angew. Chem., Int. Ed.. 2004, 43, 4349-4352.

37. Rh-Catalyzed Amination of Ethereal C-H Bonds: AVersatile Strategy for the Synthesis of Complex Amines Fiori, K. W.; Fleming, J. J.; Du Bois, J. Angew. Chem., Int. Ed.. 2004, 43, 4349-4352.

38. Rh-Catalyzed Amination of Ethereal C-H Bonds: AVersatile Strategy for the Synthesis of Complex Amines Fiori, K. W.; Fleming, J. J.; Du Bois, J. Angew. Chem., Int. Ed.. 2004, 43, 4349-4352.

39. Exploring New Uses for C-H Amination: Ni-Catalyzed Cross-Coupling of Cyclic Sulfamates Wehn, P. M.; J. J.; Du Bois, J. Org. Lett. 2005, 7, 4685-4688.

40. Exploring New Uses for C-H Amination: Ni-Catalyzed Cross-Coupling of Cyclic Sulfamates Wehn, P. M.; J. J.; Du Bois, J. Org. Lett. 2005, 7, 4685-4688.

41. Exploring New Uses for C-H Amination: Ni-Catalyzed Cross-Coupling of Cyclic Sulfamates Wehn, P. M.; J. J.; Du Bois, J. Org. Lett. 2005, 7, 4685-4688.

42. Exploring New Uses for C-H Amination: Ni-Catalyzed Cross-Coupling of Cyclic Sulfamates Wehn, P. M.; J. J.; Du Bois, J. Org. Lett. 2005, 7, 4685-4688.

43. Exploring New Uses for C-H Amination: Ni-Catalyzed Cross-Coupling of Cyclic Sulfamates Wehn, P. M.; J. J.; Du Bois, J. Org. Lett. 2005, 7, 4685-4688.

44. Oxaziridine-Mediated Catalytic Hydroxylation of Unactivated 3° C-H Bonds Using Hydrogen Peroxide Brodsky, B. H.; J. J.; Du Bois, J. J. Am. Chem. Soc. 2005, ASAP.

45. Oxaziridine-Mediated Catalytic Hydroxylation of Unactivated 3° C-H Bonds Using Hydrogen Peroxide Brodsky, B. H.; J. J.; Du Bois, J. J. Am. Chem. Soc. 2005, ASAP.

46. Oxaziridine-Mediated Catalytic Hydroxylation of Unactivated 3° C-H Bonds Using Hydrogen Peroxide Brodsky, B. H.; J. J.; Du Bois, J. J. Am. Chem. Soc. 2005, ASAP.

47. Oxaziridine-Mediated Catalytic Hydroxylation of Unactivated 3° C-H Bonds Using Hydrogen Peroxide Brodsky, B. H.; J. J.; Du Bois, J. J. Am. Chem. Soc. 2005, ASAP.

48. Oxaziridine-Mediated Catalytic Hydroxylation of Unactivated 3° C-H Bonds Using Hydrogen Peroxide Brodsky, B. H.; J. J.; Du Bois, J. J. Am. Chem. Soc. 2005, ASAP.

49. Oxaziridine-Mediated Catalytic Hydroxylation of Unactivated 3° C-H Bonds Using Hydrogen Peroxide Brodsky, B. H.; J. J.; Du Bois, J. J. Am. Chem. Soc. 2005, ASAP.

50. A Stereoselective Synthesis of (-)-Tetrodotoxin Hinman, A.; J. J.; Du Bois, J. J. Am. Chem. Soc. 2003, 125, 11510-11511.

51. A Stereoselective Synthesis of (-)-Tetrodotoxin Hinman, A.; J. J.; Du Bois, J. J. Am. Chem. Soc. 2003, 125, 11510-11511.

52. A Stereoselective Synthesis of (-)-Tetrodotoxin Hinman, A.; J. J.; Du Bois, J. J. Am. Chem. Soc. 2003, 125, 11510-11511.

53. A Stereoselective Synthesis of (-)-Tetrodotoxin Hinman, A.; J. J.; Du Bois, J. J. Am. Chem. Soc. 2003, 125, 11510-11511.

54. A Stereoselective Synthesis of (-)-Tetrodotoxin Hinman, A.; J. J.; Du Bois, J. J. Am. Chem. Soc. 2003, 125, 11510-11511.

55. A Stereoselective Synthesis of (-)-Tetrodotoxin Hinman, A.; J. J.; Du Bois, J. J. Am. Chem. Soc. 2003, 125, 11510-11511.