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Atomic Layer Deposition - ALD
Introduction Example of Al2O3 ALD at MiNaLab Deposition materials Advantages and disadvantages Summary
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Atomic Layer Deposition
Excellent thickness controll and step coverage Self-limited process Developed in 1974 First industrial use: electrolumenicent panels
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Some opportunities of ALD
Nanolaminate: ZrO2 and SiO2 Coated deep trench structure
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ALD of Al2O3 on Si
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ALD at MiNaLab Al2O3, ZnO, TiO2 Thickness: sub nm nm
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ALD – deposited materials
Oxides (Al2O3, ZnO, TiO2, HfO2 , HfSiO, La2O3, SiO2, Ta2O5) Nitrides (TiN, TaN, SiN, HfN, AlN) Sulfides (ZnS) Metals (Cu, W, Pt, Ru)
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Applications High quality photonics Thin solarcells laminate =>
Thin gate oxides with high dielectric constant Diffusion barriers and passivation of active layers Single metal coating for catalysts
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Advantages of ALD Low temperature deposition is possible
Excellent step coverage and reproducibility High density film and no pinholes Easy to scale up
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Disadvantages of ALD Expensive equipment
Critical adjustment of the flow: too much flow => clogging of valves too low flow => under-performance
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Summary ALD is excellent for: Thin films High density
Excellent stociometry controll 3D structures Large area substrates: no problem
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