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Of Elements Chemistry Chapter 5 Section 1
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http://www.privatehand.com/flash/elements. html http://www.privatehand.com/flash/elements. html
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Russian chemist Wrote own textbook in 1868-1870 Organized elements Noted properties repeated (periodicity) when organized by atomic mass
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Some 'gaps' seemed to exist in his table of approximately 60 elements Predicted new elements would be discovered to fill the gaps (1869)
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Mendeleev predicted the properties and existance of elements missing from the 'gaps' Support (matched the predicted properties well): The discovery of gallium (est. mass 68) in 1875 Discovery of scandium (est. mass 45) in 1879 Discovery of germanium (est. mass 70) in 1886
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Success of Mendeleev periodic table supports periodic law The physical and chemical properties of elements reoccur in a systematic manner Julius Lothar Meyer also proposed this in 1870
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Some elements did not line up correctly when the atomic mass was used Mendeleev moved 17 elements to line up properties instead of mass Reason for periodicity not understood in late 1800s
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Found relationship between X-ray wavelength and atomic number in 1913 (Moseley's Law) This allowed calculation of atomic number, and re- organization of elements
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Predicted existance of technetium and promethium Furthered understanding of Rare Earth Elements (Lanthanide series) Periodic table reorganized by atomic number, and problem elements were resolved
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Unknown when Mendeleev made table Argon discovered by Lord Rayleigh 1895 William Ramsey suggested argon grouped with helium in “zero group” 1898 By the turn of the century, helium, argon, neon, krypton and xenon had been discovered
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Discovered plutonium in 1940 Helped discover all transuranic elements from 94 to 102 Placed actinide series below lanthanide series on table Last major change to periodic table
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