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NUCLEAR CHEMISTRY SUROVIEC SPRING 2015 Chapter 19
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I. Types of Radiation Radioactivity was discovered in 1896 by Bequerel and further work was done by Curie and Rutherford.
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A. Isotope review X A Z Mass Number Atomic Number Element Symbol
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B. Alpha decay Alpha decay occurs when an unstable nucleus emits a particle composed of 2 protons and 2 neutrons.
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C. Beta decay Beta decay occurs when an unstable nucleus emits an electron
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D. Gamma rays Gamma ray emission is a high energy/short wavelength electromagnetic radiation.
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E. Positron emission Positron emission occurs when an unstable nucleus emits a positron
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F. Electron capture Electron capture involves a particle being absorbed by instead of ejected from an unstable nucleus
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II. Kinetics of radioactivity Radioactivity is the spontaneous emission by unstable nuclei of particle or electromagnetic radiation to get to a stable configuration. All radioactive decay is first order kinetics
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Example A tree sample has an activity of 10.1 atoms/min of carbon. If a living tree has a decay rate of 15.3 atoms/min, how old is the tree sample?
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Example Americium-241 is used in smoke detectors. Its half life is 432 years. How long will it take for 33% of the Am-241 to decay (in years)?
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III. Fission Enrico Fermi tried to synthesize a new element by bombarding uranium with neutrons
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A. Nuclear power Fission can be used to make a bomb, but in that case all of the energy is released at once.
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IV. Nuclear Fusion Fusion is the combination of 2 nuclei to form a heavier nuclei.
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IV. Radiation in everyday life Radiation absorbed dose (rad) 1 rad = 1 x 10 -5 J/g of material Roentgen equivalent for man (rem) 1 rem = 1 rad x RBE Relative Biological Effectiveness -ray = 1 = 1 = 20
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A. Uses in Medicine It is immensely useful to use radioactivity in medical diagnosis
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