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Singel particle energy from Bolztman

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Presentation on theme: "Singel particle energy from Bolztman"— Presentation transcript:

1 Singel particle energy from Bolztman
Boltzmann number of 1-particle state >>number of particles How many 1-particle states? Remember the sphere used to explain degeneracy? number of 1-particle states with an energy lower than e = number of lattice points enclosed by the sphere in the positive octant:

2 Many particles Boltzman energy
The average energy of N particles is N times the average energy of one particle

3 NON Bolztmann ensembles
yi1 yi3 yi2 Fermions: 2 particles cannot occupy the same quantum stateoccupation number nk can only be 0 or 1 P1,2y=-y antisymmetric yi2 yi3 Bosons: 2 particles can occupy the same quantum stateoccupation number nk can have any value yi4 yi6 yi5 P1,2y=+y symmetric

4 Partition functions for F or B
There are many ways of counting distributions, choose Grand-Canonical Ensemble

5 Summing with occupation numbers

6 Fermions Fermi-Dirac

7 Bosons from our outstanding math background … we recognize the series Bose-Einstein Combining Bose-Einstein with the Fermi-Dirac we obtain a gral. Eq.

8 Grand-Canonical equation

9 G-canonical equations II
Keep in mind that even though we started with non-interacting particles, there wavefunctions are symmetrized they are NOT INDEPENDENT

10 High T low r limit for n Boltzmann number of 1-particle state >>number of particles

11 High T low r limit for E

12 Example Examples: Photon gas, an electromagnetic field in thermal equilibrium with its container To describe the state of the field, we need to know how many n are in each oscillator Photons are bosons  n=0,1,2,3…..

13 Cont.

14 cont The average number of photons in a state j… Planck distribution


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