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Honors Chem Unit 10
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Kinetic Molecular Theory (KMT) Gases are made of mostly empty space and a few fast moving particles. Molecules are constantly in motion and collide Particles move faster with increased temperature
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Properties of Gases Low Density Expansion Compressibility Fluidity
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Properties of Gases Diffusion: spontaneous mixing of gases
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Properties of Gases Effusion: gas particles pass through a small opening
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Graham’s Law of Diffusion (or Effusion) “Lighter, faster, farther”
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Graham’s Law of Diffusion (or Effusion)
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Pressure (P) Collisions of particles w/ container
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Pressure Units 1 atm (atmosphere) of pressure is the average pressure at sea level 1 atm= 760 mmHg (millimeters of Mercury) = 760 torr = 101.3 kPa (kilo Pascals) = 14.7 psi (pounds per square inch)
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Volume (V) amount of space that a gas occupies Liters (L) 1 L = 1000mL
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Temperature average kinetic energy of gas particles. Kelvin (K) Celsius is not used—Why? o C + 273 = K Absolute Zero = 0 Kelvin (-273 C)
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STP STP = Standard Temperature and Pressure Exactly 0 o C and 1 atm At STP, one mole of gas (6.02 x10 23 particles) occupies 22.4 L
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The Combined Gas Law Equation
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Charles’ Law: Volume and Temp Volume increases, temperature increases Pressure and moles are held constant (toss ‘em)
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Charles’ Law: Equation Remember: Temperatures must be in Kelvin
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Charles’ Law: Graph
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Charles’ Law : Example A gas sample at 25 o C and 752 mL is heated to 50 o C, what is the new volume?
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Boyle’s Law : Pressure and Volume Pressure and Volume are inversely related. Temperature and moles are held constant (toss ‘em)
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Boyle’s Law : Equation Remember: Pressure units on both sides of the equation must be the same P 1 V 1 = P 2 V 2
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Boyle’s Law: Graph
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Boyle’s Law Example Q: A 1.0 L sample of gas is held at standard pressure, 1.0 atm. The pressure of the gas is reset to 152 mmHg. What is the new volume of the gas?
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Gay-Lussac’s Law: Pressure and Temperature Temperature and pressure are directly related Volume and moles are held constant (toss ‘em)
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Gay-Lussac’s Law: Equation
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Gay-Lussac’s Law: Graph
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Gay-Lussac’s Law: Example Q: A gas has a pressure of 0.370 atm at 50.0 °C. What is the pressure at standard temperature?
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Charles Law: Simulation
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Charles’ Law: Video Demo
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Boyle’s Law: Simulation
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Boyle’s Law: Video Clip
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Gay-Lussac’s Law: Simulation
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Gay-Lussac’s Law: Video Clip
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