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Chapter 8 Lecture 8.5 Hybridization Section 8.3 Bonding Theories
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Molecular Orbitals an orbital formed by the overlap of atomic orbitals –B–Bonding orbital Can be occupied by two electrons in a covalent bond –S–Sigma Bond –P–Pi Bond
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Sigma Bond σ Head-on overlap of two atomic orbitals Has axial symmetry
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Sigma Bond σ Hydrogen, H 2
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Sigma Bond σ Fluorine, F 2
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Pi Bond π Side by side overlap of two orbitals
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Ethene
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Ethyne H - C = C - H
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CH 4
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Hybridizaton The combination of orbitals
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sp 3
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8.3 Hybrid Orbitals sp 2 – Hybridization Involving Double Bonds
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sp 2 Ethene, C 2 H 4
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Ethene
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sp ethyne, C 2 H 2
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8.3 Hybrid Orbitals – Hybridization Involving Triple Bonds
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Ethyne H - C = C - H
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