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Unit 7 Gas Laws
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Gases Gases (g): Transparent, compressible, expand without limit, have no shape/volume. **Take the shape and volume of their container.
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Gases exert pressure: STP: defined as standard temperature and pressure *Found on Table A 1atm 101.3kPa *Pressure can also be 760 torr or 760 mm Hg
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Kinetic Molecular Theory of Gases Ideal Gas Laws Ideal gases are those whose gas particles (molecules): travel in random, constant, straight line motion. (*At absolute zero, all kinetic energy ceases, so all particles stop moving.)
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are separated by great distances relative to the size of the molecule so that the volume of the actual molecule is considered negligible.
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have no real attractive forces between them. have collisions that may result in the transfer of energy between particles {but remember overall energy is conserved} ENERGY
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Real Gases Real gases do have volumes and do exhibit attractive forces between their particles or we would have no atmosphere!
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For real gases to behave like ideal gases: Temperature must be high Pressure must be low The two most common real gases that behave most like ideal gases are H 2 and He because they are the smallest and least dense
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Avagadro’s Hypothesis under the same conditions of temperature and pressure, 2 equal volumes of two different gases will have the same number of particles regardless of their masses. At STP, this number of particles is Avogadro’s number, which is 6.02 x 10 23
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The Combined Gas Law The pressure a gas exerts on its surroundings is related to its temperature and volume such that: FORMULA: P 1 V 1 = P 2 V 2 T 1 T 2 *note* Temperature must be in KELVIN!!! Pressure 1 and 2 and Volume 1 and 2 must be in the same units. See examples
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Boyle’s Law As long as temperature remains constant, pressure and volume of a gas will affect each other inversely FORMULA: P 1 V 1 = P 2 V 2 See example
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Charles Law As long as the pressure on a given mass of a gas remains constant, the temperature and volume will affect each other directly. FORMULA: V 1 = V 2 T 1 T 2 See example Temp Vol
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Gay-Lussac’s Law As song as the volume of a given mass of a gas remains constant, the temperature and pressure will affect each other directly. FORMULA: P 1 = P 2 T 1 T 2 To graph this relationship: Pressure Temp
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